In the given reaction sequence, the amount of R produced (in g) is ________. 
(Given: molar mass (in g $mol^{-1}$) of H = 1, C = 12, N = 14, O = 16, and S = 32)
(rounded off to two decimal places)
This is a sequential organic synthesis problem where we track the moles of the limiting reactant (Benzene) through three steps, calculating the yield and molecular weight changes at each stage.
Benzene formula: $\text{C}_6\text{H}_6$.
Molar Masses (g/mol): $\text{H}=1, \text{C}=12$.
$$MW_{\text{Benzene}} = 6(12) + 6(1) = 78 \text{ g/mol}$$
Initial mass of Benzene: $7.8 \text{ g}$.
$$\text{Moles of Benzene} = \frac{7.8 \text{ g}}{78 \text{ g/mol}} = 0.10 \text{ mol}$$
At high temperature ($200^\circ\text{C}$), sulfonation of Benzene yields 1,3-Benzenedisulfonic acid ($\text{C}_6\text{H}_4(\text{SO}_3\text{H})_2$). The reaction is assumed to be substitution of two $\text{H}$ by two $\text{SO}_3\text{H}$ groups.
$$MW_{\text{P}} = MW_{\text{Benzene}} - 2\cdot 1 + 2 \cdot (\text{S} + 3\text{O} + \text{H})$$
$$MW_{\text{P}} = 78 - 2 + 2(32 + 3\cdot 16 + 1) = 76 + 2(81) = 76 + 162 = 238 \text{ g/mol}$$
Yield: $80\%$.
$$\text{Moles of P} = 0.10 \text{ mol} \times 0.80 = 0.080 \text{ mol}$$
Benzenedisulfonic acid ($\text{P}$) reacts with $\text{NaOH}$ fusion to replace the sulfonate groups ($\text{SO}_3\text{H}$) with hydroxyl groups ($\text{OH}$), followed by acidification, yielding Resorcinol (1,3-Dihydroxybenzene, $\text{C}_6\text{H}_4(\text{OH})_2$).
$$MW_{\text{Q}} = MW_{\text{Benzene}} - 2 \cdot 1 + 2 \cdot (\text{O} + \text{H})$$
$$MW_{\text{Q}} = 78 - 2 + 2(16 + 1) = 76 + 34 = 110 \text{ g/mol}$$
Yield: $75\%$.
$$\text{Moles of Q} = 0.080 \text{ mol} \times 0.75 = 0.060 \text{ mol}$$
Resorcinol ($\text{Q}$) is highly activated. Excess nitrating mixture substitutes all available positions (2, 4, 6 positions relative to $\text{OH}$ groups are active). Assuming complete nitration of all free positions (2, 4, 6, 5), but based on standard chemistry, Resorcinol yields 2,4,6-trinitroresorcinol (Styphnic acid, $\text{C}_6(\text{NO}_2)_3(\text{OH})_2\text{H}$). Wait, only three positions are substituted (2, 4, 6 positions relative to the two $\text{OH}$ groups). The final product $\text{R}$ is 2,4,6-trinitroresorcinol.
Formula of $\text{R}$ ($\text{C}_6(\text{OH})_2\text{H}_3(\text{NO}_2)_3$): $\text{C}_6\text{H}_3\text{O}_2(\text{NO}_2)_3$.
Change: $3 \text{ H}$ atoms replaced by $3 \text{ NO}_2$ groups.
$$MW_{\text{R}} = MW_{\text{Q}} - 3\cdot 1 + 3 \cdot (\text{N} + 2\text{O})$$ $$MW_{\text{R}} = 110 - 3 + 3 \cdot (14 + 32) = 107 + 3 \cdot 46$$ $$MW_{\text{R}} = 107 + 138 = 245 \text{ g/mol}$$
Yield: $50\%$.
$$\text{Moles of R} = 0.060 \text{ mol} \times 0.50 = 0.030 \text{ mol}$$
$$\text{Mass of R} = \text{Moles of R} \times MW_{\text{R}}$$ $$\text{Mass of R} = 0.030 \text{ mol} \times 245 \text{ g/mol}$$ $$\text{Mass of R} = 7.35 \text{ g}$$
The amount of $\text{R}$ produced is $7.35 \text{ g}$. Rounding off to two decimal places gives 7.35.
This matches the provided constraint range [7.35, 7.35].
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