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Question

In the following reaction

 the major product [X] is

The correct answer is

The reaction depicted in the image appears to undergo an aldol condensation. Let's break down the steps involved:

  1. Reagents and Reaction Conditions:

    • Cyclohexanone (a ketone) is reacted with benzaldehyde (an aldehyde).
    • NaCN is used as a catalyst in DMF (dimethylformamide).
  2. Mechanism: This is a typical crossed aldol reaction where:

    • Cyclohexanone forms an enolate ion in the presence of NaCN.
    • The enolate ion attacks the carbonyl carbon of benzaldehyde.
    • This nucleophilic addition forms a beta-hydroxy ketone.
    • Under the reaction conditions, dehydration occurs, resulting in the formation of an α,β-unsaturated ketone.
  3. Product Formation:

    • The major product [X] is a conjugated system where the double bond forms between the alpha and beta carbons relative to the ketone.

Conclusion: Based on the steps above, the major product [X] is formed through aldol condensation and dehydration. The structure of the major product is:

This structure represents the α,β-unsaturated ketone derived from cyclohexanone and benzaldehyde.

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Important Questions from Organic Transformations

  1. The major product formed in the following reaction sequence is

  2. The major product formed in the following reaction sequence is

  3. The major products X and Y in the following reaction sequence are 

  4. The following conversion is an example of 

  5. The major product formed in the reaction given below is

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