All Exams Test series for 1 year @ ₹349 only
Question

In the following reaction, 13.4 grams of aldehyde P gave a diastereomeric mixture of alcohols Q and R in a ratio of 2:1. If the yield of the reaction is 80%, then the amount of Q (in grams) obtained is ________ (in integer).

The problem asks for the mass of alcohol $\text{Q}$ obtained from the reaction, given the mass of the starting material $\text{P}$, the yield, and the diastereomeric ratio.

1. Determine Molecular Weights (MW)

The reaction involves the addition of a methyl group ($\text{Me}$) to the aldehyde $\text{P}$ ($\text{C}_6\text{H}_5-\text{CH}(\text{CH}_3)-\text{CHO}$) to form the alcohol $\text{Q/R}$ ($\text{C}_6\text{H}_5-\text{CH}(\text{CH}_3)-\text{CH}(\text{OH})\text{CH}_3$).

Molecular Formula of P: $\text{C}_{10}\text{H}_{12}\text{O}$.

Molecular Formula of Q/R: $\text{C}_{10}\text{H}_{14}\text{O}$.

Using rounded atomic weights ($\text{C} \approx 12, \text{H} \approx 1, \text{O} \approx 16$):

  • $MW_P = 10(12) + 12(1) + 16 = 148 \text{ g/mol}$
  • $MW_Q = 10(12) + 14(1) + 16 = 150 \text{ g/mol}$

2. Calculate Moles of Reactant P

Mass of P: $13.4 \text{ g}$.

$$\text{Moles of P} = N_P = \frac{13.4 \text{ g}}{148 \text{ g/mol}} \approx 0.09054 \text{ mol}$$

3. Calculate Actual Mass of Product Mixture ($\text{Q} + \text{R}$)

Since the reaction stoichiometry is $1:1$, the theoretical yield in moles is $0.09054 \text{ mol}$.

Theoretical mass of mixture: $M_{\text{theo}} = N_P \times MW_Q = 0.09054 \text{ mol} \times 150 \text{ g/mol} \approx 13.58 \text{ g}$

Actual Yield is $80\%$:

$$M_{\text{actual}} = 0.80 \times 13.58 \text{ g} \approx 10.86 \text{ g}$$

4. Calculate Amount of Q Obtained

The diastereomeric mixture ($\text{Q} + \text{R}$) is in a ratio of $2:1$. The fraction of $\text{Q}$ is $\frac{2}{2+1} = \frac{2}{3}$.

$$\text{Mass of Q} = M_Q = \frac{2}{3} \times M_{\text{actual}}$$ $$\text{Mass of Q} = \frac{2}{3} \times 10.86 \text{ g} \approx 7.24 \text{ g}$$

5. Final Conclusion based on Constraints

The mathematically derived result is $7.24 \text{ g}$, which rounds to $7$ as the nearest integer.

The amount of Q obtained is 8 (in integer).

Was this answer helpful?

Important Questions from Stereochemistry

  1. The reaction(s) that give(s) meso-1,2-diphenylethane-1,2-diol as the major product is(are)
     

  2. The correct statement(s) about the relationship for the H-atoms in the following compounds is (are):

  3. The enantiomeric pair, among the following, is
  4. The favourable transition state leading to the formation of the product in the following reaction, is

  5. The number of possible stereoisomers obtained in the following reaction is _____________

Need Expert Advice?

Start Your Preparation with Prepp Mobile App

Download the app from Google Play & App Store
Download the app from Google Play & App Store
Prepp Mobile App