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Question

In terms of their magnetic properties, the elements named nickel and cobalt are classified as:

This question was previously asked in
SSC Stenographer 2020-21 Previous Year Paper (15-Nov-2021) (Shift 2)
The correct answer is

ferromagnetic

Understanding Magnetic Properties of Elements

Materials exhibit different magnetic behaviors when placed in a magnetic field. These behaviors are classified based on how strongly and in what direction the material becomes magnetized. The main classifications include diamagnetism, paramagnetism, ferromagnetism, antiferromagnetism, and ferrimagnetism.

Classifying Magnetic Materials

Let's briefly look at the key types of magnetic materials:

  • Diamagnetic Materials: These materials are weakly repelled by a magnetic field. They have no permanent magnetic dipoles in the absence of an external field. When a field is applied, they develop an induced magnetic moment opposite to the field direction. Examples include water, gold, copper, and noble gases.
  • Paramagnetic Materials: These materials are weakly attracted to a magnetic field. They have permanent magnetic dipoles, but these dipoles are randomly oriented in the absence of a field, resulting in no net magnetization. When a field is applied, the dipoles align partially with the field direction, causing a weak attraction. Examples include aluminum, oxygen, and platinum.
  • Ferromagnetic Materials: These materials are strongly attracted to a magnetic field. They have permanent magnetic dipoles that align spontaneously in regions called magnetic domains, even without an external field. When an external field is applied, these domains align with the field, leading to very strong magnetization. They can retain their magnetization after the external field is removed, becoming permanent magnets.
  • Anti-ferromagnetic Materials: In these materials, neighboring atomic magnetic dipoles align in opposite directions, canceling each other out. This results in a very weak net magnetic moment, often similar to paramagnetic behavior overall, but arising from a different internal structure. Examples include chromium and manganese oxide.

Nickel and Cobalt: Ferromagnetic Elements

The question asks about the magnetic properties of nickel and cobalt. These elements, along with iron, are well-known examples of ferromagnetic materials. Their atoms have magnetic moments that strongly interact, causing them to align in parallel within domains. This strong internal alignment is responsible for their characteristic strong attraction to magnets and their ability to be permanently magnetized.

Analyzing the Options for Nickel and Cobalt

Given the classifications and the known properties of nickel and cobalt, let's consider the provided options:

  1. anti-ferromagnetic: This classification involves opposing alignment of magnetic moments, which is not the dominant behavior for nickel and cobalt exhibiting strong net magnetization.
  2. diamagnetic: Diamagnetic materials are weakly repelled by magnets. Nickel and cobalt are strongly attracted.
  3. ferromagnetic: This classification describes materials with strong attraction to magnets and the ability to become permanently magnetized due to spontaneous alignment of magnetic moments within domains. This accurately describes nickel and cobalt.
  4. paramagnetic: Paramagnetic materials are only weakly attracted to magnets. Nickel and cobalt are strongly attracted.

Based on the properties of nickel and cobalt, the classification that best fits them is ferromagnetic.

Comparison of Magnetic Materials
Property Diamagnetic Paramagnetic Ferromagnetic
Interaction with Magnetic Field Weakly repelled Weakly attracted Strongly attracted
Permanent Dipoles No Yes (randomly oriented) Yes (aligned in domains)
Ability to form Permanent Magnets No No Yes
Examples Water, Gold, Copper Aluminum, Oxygen, Platinum Iron, Nickel, Cobalt

Conclusion on Nickel and Cobalt Classification

Nickel and cobalt are classic examples of ferromagnetic substances. Their magnetic behavior is characterized by strong attraction to magnetic fields and the ability to become permanent magnets under certain conditions. This puts them firmly in the ferromagnetic category.

Revision Table: Magnetic Properties Study

Key Magnetic Material Categories
Category Response to External Field Domain Structure
Diamagnetic Weak repulsion No domains; induced moment opposes field
Paramagnetic Weak attraction No domains; random moments align with field
Ferromagnetic Strong attraction Domains with parallel moments; domains align with field
Anti-ferromagnetic Very weak interaction (like paramagnetic) Domains with anti-parallel moments; net moment near zero

Additional Information: Curie Temperature and Ferromagnetism

Ferromagnetic materials exhibit ferromagnetism below a specific temperature called the Curie temperature (TC). Above the Curie temperature, the thermal energy is sufficient to overcome the strong exchange interaction that causes the spontaneous alignment of magnetic dipoles within domains. When heated above its Curie temperature, a ferromagnetic material loses its ferromagnetic properties and behaves like a paramagnetic material.

  • For Iron (Fe), TC ≈ 1043 K (770 °C).
  • For Cobalt (Co), TC ≈ 1388 K (1115 °C).
  • For Nickel (Ni), TC ≈ 631 K (358 °C).

This temperature dependency is a crucial characteristic of ferromagnetic materials.

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