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Question

Why are half-filled orbitals considered more stable?

The correct answer is

Equal electron distribution reduces repulsion in orbitals

Electronic configurations show a special preference for exactly half-filled (p³, d⁵, f⁷) and completely filled (p⁶, d¹⁰, f¹⁴) subshells because these arrangements possess extra stability compared to other, unevenly filled distributions.

Two main reasons are usually cited:

  • Symmetrical charge distribution: When every degenerate orbital of a subshell (say the three p-orbitals or the five d-orbitals) holds exactly one electron, the electron density around the nucleus is distributed evenly in space. This symmetry lowers electron–electron repulsion and shields the nucleus more uniformly, which in turn lowers the overall energy of the atom.
  • Maximum exchange energy: Electrons occupying different orbitals of the same subshell but having parallel spins can exchange their positions without violating the Pauli exclusion principle. Each such possible exchange between two electrons of parallel spin releases a small, quantifiable amount of stabilization energy called exchange energy. A half-filled subshell has the maximum possible number of electrons with parallel spin (one per orbital, per Hund's rule of maximum multiplicity), and therefore the maximum number of possible exchanges — giving it the lowest energy and hence the greatest stability among partially filled configurations.

This is precisely why several elements show "anomalous" configurations that sacrifice the normal (n)s²(n-1)d⁴ or d⁹ filling order to instead achieve a half-filled or fully-filled d-subshell: chromium adopts [Ar]3d⁵4s¹ instead of [Ar]3d⁴4s², and copper adopts [Ar]3d¹⁰4s¹ instead of [Ar]3d⁹4s², because one electron is "promoted" from the 4s orbital to complete the more stable d⁵ or d¹⁰ arrangement.

Now consider why the correct choice — that equal electron distribution reduces repulsion in the orbitals — is the right description: it directly captures both the symmetry argument and the reduced-repulsion consequence that make half-filled subshells stable.

The other options can be ruled out as follows:

  • Claiming half-filled orbitals are always less stable contradicts the well-documented anomalous configurations of Cr, Mo, Cu, Ag, etc., where atoms rearrange electrons specifically to attain a half-filled or fully-filled state because it lowers energy.
  • Saying stability does not depend on electron arrangement ignores the entire basis of exchange energy and Hund's rule, both of which show that how electrons are arranged among degenerate orbitals directly affects the atom's total energy.
  • The statement that unequal distribution increases atomic instability is a distractor that sounds plausible but is not itself an explanation of why half-filled orbitals are stable — it simply restates the effect without identifying the symmetry/exchange-energy cause, and unequal distributions are not always "unstable" in a strict sense, only relatively higher in energy than the symmetric case.
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Similar Questions

  1. What does the Aufbau principle state about electron filling in orbitals?

  2. Two atoms having the same number of nucleons but different atomic numbers are called ________.

  3. According to the Heisenberg uncertainty principle, what happens when the precision in measuring position increases?

  4. The charge of an electron is best described as:

  5. Cathode rays observed in discharge tubes are best described as:

  6. Proton discovery is associated with which observation in discharge tube experiments?

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  8. Isotopes of the same element possess different atomic masses because they contain different numbers of ________.

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Important Questions from Structure of Atom

  1. Identify the element having zero valency

  2. The atomic number of an element is 8. How many electrons will it gain to form a compound with sodium?

  3. An atom of carbon has 6 protons. Its mass number is 12. How many neutrons are present in an atom of carbon?

  4. What is the atomic number of nitrogen?

  5. What are isobars?

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