According to Bohr's model for the hydrogen atom, the radius ($r_n$) of an electron's orbit is determined by the principal quantum number ($n$). The relationship is:
$r_n = \frac{n^2 a_0}{Z}$
For hydrogen ($Z=1$), this simplifies to $r_n = n^2 a_0$, meaning the radius is proportional to the square of the orbit number ($r_n \propto n^2$).
Option D presents the statement: "Radius of $3^{rd}$ orbit is nine times larger than that of $1^{st}$ orbit". We verify this using the derived relationship.
Radius of the $3^{rd}$ orbit ($n=3$):
$r_3 = 3^2 a_0 = 9 a_0$
Radius of the $1^{st}$ orbit ($n=1$):
$r_1 = 1^2 a_0 = 1 a_0$
Comparing the two radii:
$\frac{r_3}{r_1} = \frac{9 a_0}{1 a_0} = 9$
Thus, $r_3 = 9 \times r_1$. This confirms the statement that the radius of the $3^{rd}$ orbit is nine times that of the $1^{st}$ orbit.
$CaCO_3(s) + 2HCl(aq) \rightarrow CaCl_2(aq) + CO_2(g) + H_2O(l)$
Consider the above reaction, what mass of $CaCl_2$ will be formed if 250 mL of 0.76 M HCl reacts with 1000 g of $CaCO_3$ ?
(Given: Molar mass of Ca, C, O, H and Cl are 40, 12, 16, 1 and 35.5 g $mol^{-1}$, respectively)

Two vessels A and B are connected via stopcock. The vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and is allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true ?
Which of the following graphs correctly represents the plot of $K_H$ at 1 bar for gases in water versus temperature?
If equal volumes of $AB_2$ and $XY$ (both are salts) aqueous solutions are mixed, which of the following combination will give a precipitate of $AY_2$ at 300 K ?
(Given $K_{sp}$ (at 300 K) for $AY_2=5.2 \times 10^{-7}$)
On complete combustion 1.0 g of an organic compound (X) gave 1.46 g of $CO_2$ and 0.567 g of $H_2O$. The empirical formula mass of compound (X) is ________ g.
(Given molar mass in g $mol^{-1}$ C: 12, H: 1, O: 16)
Consider the following electrochemical cell at standard condition.
$Au(s)$|$QH_2,Q$| $NH_4X(0.01 M)$ | | $Ag^+ (1M)$|$Ag(s)$ $E_{cell}$ = +0.4 V
The couple $QH_2/Q$ represents quinhydrone electrode, the half cell reaction is given below : 
[Given: $E_{Ag^+/Ag}^ \circ$ = +0.8 V and $\frac{2.303RT}{F}$ = 0.06 V ]
The $pK_b$ value of the ammonium halide salt ($NH_4X$) used here is ________. (nearest integer)
For the reaction A $\rightarrow$ products. 
The concentration of A at 10 minutes is ________ $\times10^{-3}$ mol $L^{-1}$ (nearest integer).
The reaction was started with 2.5 mol $L^{-1}$ of A.
Consider the following equilibrium,
$CO(g) + 2H_2(g) = CH_3OH(g)$
0.1 mol of CO along with a catalyst is present in a 2 $dm^3$ flask maintained at 500 K. Hydrogen is introduced into the flask until the pressure is 5 bar and 0.04 mol of $CH_3OH$ is formed. The $K_{p}^\theta$ is ________ $\times10^{-3}$ (nearest integer).
Given: R=0.08 $dm^3$ bar $K^{-1}$ $mol^{-1}$
Assume only methanol is formed as the product and the system follows ideal gas behaviour.
0.1 mol of the following given antiviral compound (P) will weigh ________ $\times10^{-1}g$ (nearest integer). 
(Given : molar mass in g $mol^{-1}$ H : 1, C: 12, N : 14, O: 16, F: 19, I : 127)
Among $10^{-9}$ g (each) of the following elements, which one will have the highest number of atoms? Element: Pb, Po, Pr and Pt
$CaCO_3(s) + 2HCl(aq) \rightarrow CaCl_2(aq) + CO_2(g) + H_2O(l)$
Consider the above reaction, what mass of $CaCl_2$ will be formed if 250 mL of 0.76 M HCl reacts with 1000 g of $CaCO_3$ ?
(Given: Molar mass of Ca, C, O, H and Cl are 40, 12, 16, 1 and 35.5 g $mol^{-1}$, respectively)

Two vessels A and B are connected via stopcock. The vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and is allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true ?
Which of the following graphs correctly represents the plot of $K_H$ at 1 bar for gases in water versus temperature?
If equal volumes of $AB_2$ and $XY$ (both are salts) aqueous solutions are mixed, which of the following combination will give a precipitate of $AY_2$ at 300 K ?
(Given $K_{sp}$ (at 300 K) for $AY_2=5.2 \times 10^{-7}$)
On complete combustion 1.0 g of an organic compound (X) gave 1.46 g of $CO_2$ and 0.567 g of $H_2O$. The empirical formula mass of compound (X) is ________ g.
(Given molar mass in g $mol^{-1}$ C: 12, H: 1, O: 16)