A complex that possess 5D ground term symbol for its metal ion is :
[Cr(H2O)6]2+
A 5D term has spin multiplicity 5 (four unpaired electrons, S = 2) and L = 2. It is the ground term of d4 and d6 ions, and a complex keeps this quintet ground state only when the ligand field is weak enough for the ion to stay high spin; in an octahedral field the 5D term becomes 5Eg (d4) or 5T2g (d6).
Step 1 — [Cr(H2O)6]2+: Cr(II) is d4; water is a weak-field ligand, so the complex is high spin, t2g3eg1, with four unpaired electrons and a ground state derived from 5D.
Step 2 — [Mn(CN)6]3– is d4 but strong-field cyanide makes it low spin, t2g4, with two unpaired electrons and a triplet (3T1g) ground state. [Fe(CN)6]4– is low-spin d6, t2g6, diamagnetic with a 1A1g ground state. [Co(H2O)6]2+ is high-spin d7, whose ground term is 4F, not a D term.
[Cr(H2O)6]2+ option is correct.
The hybridization for the complex ion [FeF6]3- and [Fe(CN)6]3- is :
Which of the following diatomic molecules is paramagnetic ?
Size of the d orbitals for Si, P, S and Cl follow the order :
The molecules P4 and CH4 exhibit the same :
The bond order for O2 and the hypothetical molecules N2- and O2+ will follow the trend :
According to CFT, Ni2+ can have two unpaired electrons in :
Which of the following complexes will NOT exhibit ideal octahedral geometry ?
The carbonyl stretching frequency (νCO) for the complexes (i) [Co(CO)4]- (ii) [Ni(CO)4] and (iii) [Fe(CO)4]2- will follow the trend :
The spin only magnetic moment for the complex Hg[Co(SCN)4] is :
The molecular formula for sodium bis (thiosulphato) argentate (I) is :
.................... is a client server application that identifies each host on the internet with a unique user-friendly name.
Every OS has a ................ or .......... which primarily resides in the main memory of the computer to perform some of the basic functions of the OS.
(i) Kernel
(ii) Interface
(iii) Nucleus
(iv) Compiler
Codes:
Which of the following are referred to as low level language?
(i) Machine language
(ii) Assembly language
(iii) High level language
(iv) Natural language
Codes:
Match the following:
| List I | List II |
| (a) New York Public Library | (i) Shelv AR |
| (b) Miami University Augmented Research Group | (ii) Smart library |
| (c) Oula University Library | (iii) Wolf Walk |
| (d) North Carolina State University | (iv) Find the future |
Codes:
Which part of the QR code represents the encoded data?