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Question

Which one of the following is not used as fertilizer?

This question was previously asked in
NDA I 2018 GAT Previous Year Paper (22-Apr-2018)
The correct answer is

Ammonium sulphide

Understanding Fertilizers and Ammonium Compounds

Fertilizers are substances that provide nutrients to plants, helping them grow better. Plants need various elements for healthy growth, primarily nitrogen (N), phosphorus (P), and potassium (K). Many fertilizers contain compounds of these elements.

The question asks which of the given ammonium compounds is NOT used as a fertilizer. Let's look at each option:

Analysis of Ammonium Compounds as Fertilizers

  • Ammonium Nitrate (\(NH_4NO_3\)): This compound is a very common fertilizer because it provides two forms of nitrogen: ammonium nitrogen and nitrate nitrogen. Both are easily absorbed by plants, making it an effective nitrogen source for crops.
  • Ammonium Sulphide (\((NH_4)_2S\)): This compound is generally NOT used as a fertilizer. Sulphides can be toxic to plants and many beneficial soil microorganisms at concentrations that would provide significant nitrogen. Also, ammonium sulphide is often unstable and breaks down, potentially releasing unpleasant or toxic gases.
  • Ammonium Phosphate (\((NH_4)_3PO_4\) or related forms like \((NH_4)_2HPO_4\)): These compounds are excellent fertilizers because they provide both nitrogen (in the ammonium form) and phosphorus (in the phosphate form), two essential macronutrients for plant growth.
  • Ammonium Sulphate (\((NH_4)_2SO_4\)): This is another widely used fertilizer. It provides nitrogen in the ammonium form and also supplies sulfur, which is an essential micronutrient for plants. It is particularly useful in sulfur-deficient soils.

Comparing the uses, ammonium nitrate, ammonium phosphate, and ammonium sulphate are all well-established fertilizers providing essential plant nutrients (Nitrogen, Phosphorus, Sulfur). Ammonium sulphide, however, is not used in agriculture as a fertilizer due to potential toxicity and instability issues.

Conclusion on Fertilizer Use

Based on their properties and common agricultural applications, ammonium sulphide is the compound from the list that is not typically used as a fertilizer.

Ammonium Compound Chemical Formula Used as Fertilizer? Nutrients Provided
Ammonium Nitrate \(NH_4NO_3\) Yes Nitrogen (N)
Ammonium Sulphide \((NH_4)_2S\) No Potential Nitrogen (but toxic/unstable)
Ammonium Phosphate \((NH_4)_3PO_4\) or \((NH_4)_2HPO_4\) Yes Nitrogen (N), Phosphorus (P)
Ammonium Sulphate \((NH_4)_2SO_4\) Yes Nitrogen (N), Sulfur (S)

Revision Table: Types of Fertilizers and Nutrients

Nutrient Role in Plants Common Fertilizer Sources
Nitrogen (N) Essential for leaf growth, chlorophyll formation Urea, Ammonium Nitrate, Ammonium Sulphate, Ammonium Phosphate, Manure
Phosphorus (P) Important for root development, flowering, fruiting, energy transfer Superphosphate, Triple Superphosphate, Ammonium Phosphate
Potassium (K) Helps with water uptake, disease resistance, overall plant vigor Potassium Chloride (Muriate of Potash), Potassium Sulphate
Sulfur (S) Component of amino acids and vitamins, aids in chlorophyll formation Ammonium Sulphate, Gypsum

Additional Information on Fertilizer Safety and Use

Proper use of fertilizers is crucial for plant health and environmental protection. Overuse can lead to nutrient runoff, polluting water bodies and harming ecosystems. Different plants have different nutrient requirements, and soil testing can help determine the appropriate type and amount of fertilizer needed.

Fertilizers can be inorganic (like the ammonium salts discussed) or organic (like compost or manure). Both types provide nutrients but differ in how quickly they release them and their impact on soil structure and microbial life.

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