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Question

Which one among the following compounds has a sweet and fruity smell?

This question was previously asked in
NDA 2 2024 GAT Question Paper (01-Sep-2024)
The correct answer is Ethyl acetate

Understanding Compound Smells

The question asks us to identify the compound among the given options that possesses a sweet and fruity smell. Different chemical compounds have distinct odors, which can often be used as a preliminary way to identify them.

Analyzing the Options

Let's look at the characteristic smells of each compound provided in the options:
  • Ethyl alcohol (Ethanol): Ethyl alcohol is a common alcohol. It has a characteristic strong, pungent, alcoholic odor. It is definitely not described as sweet and fruity.
  • Acetic acid: Acetic acid is a carboxylic acid and is the main component of vinegar. It has a very strong, sharp, pungent smell, typically described as vinegar-like. This does not fit the sweet and fruity description.
  • Ethyl acetate: Ethyl acetate is an ester. Esters are a class of organic compounds that are well-known for their pleasant, often fruity or floral, smells. Ethyl acetate specifically has a characteristic sweet, fruity smell, often compared to pear or apple. It is widely used as a solvent and in artificial flavorings and fragrances because of this aroma.
  • Acetophenone: Acetophenone is an aromatic ketone. It has a sweet, pleasant smell, often described as floral (like jasmine or orange blossom) with a slightly pungent note. While sweet, its smell is usually not categorized as primarily "fruity" compared to many esters like ethyl acetate.

Comparing the Smells

Based on the typical smells of these compounds, Ethyl acetate is the one that most closely matches the description of having a sweet and fruity smell. Esters are particularly noted for these types of pleasant aromas.
Compound Typical Smell Description
Ethyl alcohol Pungent, alcoholic
Acetic acid Strong, pungent, vinegar-like
Ethyl acetate Sweet, fruity (pear, apple-like)
Acetophenone Sweet, floral (jasmine, orange blossom), sometimes pungent

Therefore, among the given options, Ethyl acetate is the compound known for its sweet and fruity smell.

Revision Table: Identifying Chemical Smells

Compound Type Common Functional Group Typical Smells Example
Alcohols -OH Pungent, alcoholic Ethyl alcohol
Carboxylic Acids -COOH Sharp, pungent, vinegar-like Acetic acid
Esters -COO- Sweet, fruity, floral, pleasant Ethyl acetate
Ketones R-CO-R' Varied; some sweet/floral, some pungent Acetophenone

Additional Information: Esters and Fruity Smells

Esters are organic compounds formed from the reaction of a carboxylic acid and an alcohol, typically in the presence of an acid catalyst. This reaction is called esterification.

The general formula for an ester is R-COO-R', where R and R' are alkyl or aryl groups. The "R-COO-" part comes from the carboxylic acid, and the "-R'" part comes from the alcohol.

Many naturally occurring flavors and fragrances are due to esters. Here are a few examples of esters and the smells they are often associated with:

  • Methyl butanoate: Apple, pineapple
  • Ethyl butanoate: Pineapple, strawberry
  • Pentyl acetate (Amyl acetate): Banana, pear
  • Octyl acetate: Orange

These examples illustrate why Ethyl acetate, being an ester, is characterized by a sweet and fruity smell. Its specific structure (derived from ethanol and acetic acid) gives it its particular aroma.

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