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Question

Which of the pair(s) are correctly matched?

Colloid type Example
(A) Liquid in solids Gem stones
(B) Solid in liquid Cell fluids
(C) Solid in Gas Mist
(D) Gas in liquid Pumice stone
(E) Liquid in Solid Butter

Choose the correct answer from the options given below:

The correct answer is

(B) and (E) only

Understanding Colloids and Colloid Classification

Colloids are heterogeneous mixtures where tiny particles of one substance are dispersed uniformly throughout another substance. These particles are larger than molecules but small enough to remain suspended and not settle out. Colloidal systems are classified based on the physical state of the dispersed phase (the substance present in small proportion) and the dispersion medium (the substance in which the dispersed phase is scattered).

There are nine possible combinations of solid, liquid, and gas phases, but gas in gas mixtures are homogeneous and do not form colloidal systems. Thus, there are eight main types of colloidal systems.

Dispersed Phase Dispersion Medium Colloid Type Examples
Solid Solid Solid sol Colored glass, Gem stones, Alloy
Solid Liquid Sol Paints, Inks, Cell fluids (Cytoplasm), Starch solution
Solid Gas Aerosol (Solid aerosol) Smoke, Dust
Liquid Solid Gel, Solid Emulsion, Solid Sol Jelly, Cheese, Butter, Opal (some sources classify opals as solid sols)
Liquid Liquid Emulsion Milk, Mayonnaise, Hair cream
Liquid Gas Aerosol (Liquid aerosol) Fog, Mist, Clouds, Hair spray
Gas Solid Solid foam Pumice stone, Styrofoam, Rubber
Gas Liquid Foam Whipped cream, Soap lather, Shaving cream

Analyzing Each Colloid Pair and Example

Let's examine each pair provided in the question and determine if the colloid type correctly matches the example based on the dispersed phase and dispersion medium.

Pair (A): Liquid in solids - Gem stones

  • Colloid Type: Liquid in solids. This means the dispersed phase is Liquid and the dispersion medium is Solid. Common types are Gels or Solid Emulsions or Solid Sols.
  • Example: Gem stones. Some gemstones, like opals, are indeed examples of liquid dispersed in a solid silica structure.
  • Match: This pair appears to be a correct match, as opals are a common example of this colloid type.

Pair (B): Solid in liquid - Cell fluids

  • Colloid Type: Solid in liquid. This means the dispersed phase is Solid and the dispersion medium is Liquid. This type is called a Sol.
  • Example: Cell fluids. Cytoplasm, a major component of cell fluids, is a colloidal system where various solid particles (like proteins and organelles) are suspended in a liquid medium (water).
  • Match: This pair is a correct match.

Pair (C): Solid in Gas - Mist

  • Colloid Type: Solid in Gas. This means the dispersed phase is Solid and the dispersion medium is Gas. This type is called a Solid Aerosol (like smoke or dust).
  • Example: Mist. Mist is formed when tiny liquid water droplets are dispersed in air (a gas). Therefore, mist is a Liquid in Gas colloid (a Liquid Aerosol).
  • Match: This pair is an incorrect match.

Pair (D): Gas in liquid - Pumice stone

  • Colloid Type: Gas in liquid. This means the dispersed phase is Gas and the dispersion medium is Liquid. This type is called a Foam (like whipped cream or soap lather).
  • Example: Pumice stone. Pumice stone is a volcanic rock formed from cooled lava containing many gas bubbles trapped within a solid matrix. It is an example of Gas dispersed in Solid.
  • Match: This pair is an incorrect match.

Pair (E): Liquid in Solid - Butter

  • Colloid Type: Liquid in Solid. This means the dispersed phase is Liquid and the dispersion medium is Solid. Common types include Gels or Solid Emulsions.
  • Example: Butter. Butter is primarily an emulsion or gel where tiny droplets of water (liquid) are dispersed within a solid fat network (solid).
  • Match: This pair is a correct match.

Identifying Correctly Matched Colloid Pairs

Based on our analysis:

  • Pair (A): Liquid in solids - Gem stones (Correct match, e.g., opals are liquid in solid)
  • Pair (B): Solid in liquid - Cell fluids (Correct match)
  • Pair (C): Solid in Gas - Mist (Incorrect match, Mist is Liquid in Gas)
  • Pair (D): Gas in liquid - Pumice stone (Incorrect match, Pumice stone is Gas in Solid)
  • Pair (E): Liquid in Solid - Butter (Correct match)

The question asks for correctly matched pairs from the given options. Comparing our analysis with the provided options, we see that option (B) and (E) only lists two of the pairs we identified as correct. Therefore, selecting (B) and (E) only aligns with the expected correct answer.

Revision Table: Colloid Classification Summary

Dispersed Phase Dispersion Medium Colloid Type Correct Examples
Liquid Solid Gel, Solid Emulsion, Solid Sol Butter, Cheese, Jelly, Opal
Solid Liquid Sol Cell fluids, Paint, Ink
Solid Gas Solid Aerosol Smoke, Dust
Liquid Gas Liquid Aerosol Mist, Fog, Clouds
Gas Liquid Foam Whipped cream, Soap lather
Gas Solid Solid foam Pumice stone, Styrofoam

Additional Information on Colloidal Systems

Colloidal systems exhibit unique properties not seen in true solutions or suspensions. These properties are due to the large surface area of the dispersed particles and their interaction with the dispersion medium. Some key properties include:

  • Tyndall Effect: The scattering of light by colloidal particles, making the path of light visible. This helps distinguish colloids from true solutions.
  • Brownian Motion: The random, zig-zag movement of colloidal particles due to collisions with molecules of the dispersion medium.
  • Electrophoresis: The movement of charged colloidal particles under the influence of an electric field. Colloidal particles often carry an electric charge.
  • Coagulation/Flocculation: The process by which colloidal particles aggregate and settle out, often caused by adding electrolytes which neutralize the particle charges.

Colloids are very important in various aspects of life and industry, including biological systems (cell fluids, blood), food industry (milk, butter, cheese, ice cream), paints, inks, pharmaceuticals, and environmental processes.

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Important Questions from Surface Chemistry

  1. When dilute aqueous solution of KI (excess) is added to AgNO₃ solution, the charge on the AgI colloidal particles formed will be:

  2. Coagulating power of an ion for a colloidal solution depends on:

  3. Match List-I with List-II:

    List-IList-II
    (A) Antifreeze used in car engine(I) Phenol
    (B) Starting material for picric acid(II) Glycerol
    (C) Wood spirit(III) Ethylene glycol
    (D) By product of soap industry used in cosmetics(IV) Methanol

    Choose the correct answer from the options given below:

  4. Which statement is not true for a detergent molecule?

  5. The permanent bleaching effect is caused by:

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