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Question

The solubility product of the following type of reaction :
$Al(OH)_3 \rightarrow Al^{3+} + 3\bar{O}H$ is

The correct answer is
$Ksp = (Al^{3+})(\bar{O}H)^3$

$Al(OH)_3$ Solubility Product ($Ksp$) Derivation

The dissociation reaction for aluminum hydroxide ($Al(OH)_3$) in water is given as:

$Al(OH)_3 \rightarrow Al^{3+} + 3\bar{O}H$

The solubility product constant ($Ksp$) represents the equilibrium constant for the dissolution of a sparingly soluble ionic compound. For a general compound $M_xN_y$ that dissociates into $xM^{y+}$ ions and $yN^{x-}$ ions:

$M_xN_y(s) \rightleftharpoons xM^{y+}(aq) + yN^{x-}(aq)$

The expression for the solubility product is:

$K_{sp} = (M^{y+})^x (N^{x-})^y$

Where $(M^{y+})$ and $(N^{x-})$ represent the molar concentrations of the respective ions at saturation.

Applying this definition to the dissociation of $Al(OH)_3$:

  • The cation is $Al^{3+}$ with a stoichiometric coefficient of 1.
  • The anion is $\bar{O}H$ with a stoichiometric coefficient of 3.

Therefore, the $Ksp$ expression is:

$K_{sp} = (Al^{3+})^1 (\bar{O}H)^3$

Simplifying the expression gives:

$K_{sp} = (Al^{3+})(\bar{O}H)^3$

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Important Questions from Chemical Equilibrium

  1. The molar extinction coefficient of proline ninhydrin complex at 520 nm is 0.34 $\mu$M$^{-1}$Cm$^{-1}$. A solution of the proline ninhydrin complex has an absorbance of 0.68 in a one centimeter cuvette. The concentration ($\mu$M) of proline is
  2. The amount of a particular gas dissolved in water depends on
    (i) its solubility in water.
    (ii) its partial pressure at the air/water interface or sediment/water interface.
    (iii) the water temperature.
    (iv) the levels of salts in the water.
    Identify the correct answer :
  3. A 50 ml solution of pH = 1 is mixed with a 50 ml solution of pH = 2. The pH of the mixture will be nearly
  4. Consider the reaction $2C(s) + O_2(g) \rightleftharpoons 2CO(g)$ at equilibrium. 
    The equilibrium can be shifted towards the forward direction by

  5. Consider the reaction:
    $A+B \rightleftharpoons C$
    The unit of the thermodynamic equilibrium constant for the reaction is
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