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Question

The amount of a particular gas dissolved in water depends on
(i) its solubility in water.
(ii) its partial pressure at the air/water interface or sediment/water interface.
(iii) the water temperature.
(iv) the levels of salts in the water.
Identify the correct answer :

The correct answer is
(i), (ii), (iii) and (iv)

Factors Affecting Gas Dissolution in Water

The amount of a specific gas that dissolves in water is influenced by several environmental factors. Understanding these factors is key to explaining gas solubility.

Gas Solubility (i)

Each gas has an intrinsic solubility in water, representing the maximum amount that can dissolve under specific conditions. This is a fundamental property.

Partial Pressure (ii)

According to Henry's Law, the amount of gas dissolved is directly proportional to its partial pressure above the water. Higher pressure forces more gas molecules into the water.

Mathematically, Henry's Law can be represented as:
$P = k \cdot x$
Where '$P$' is the partial pressure of the gas, '$k$' is the Henry's law constant, and '$x$' is the mole fraction of the gas in the solution (representing the amount dissolved).

Water Temperature (iii)

Generally, the solubility of gases in water decreases as the temperature increases. Warmer water molecules have more kinetic energy, making it easier for dissolved gas molecules to escape into the atmosphere.

Salt Levels (iv)

The presence of dissolved salts, or salinity, affects gas solubility. Increasing salt concentration typically lowers the solubility of most non-polar gases in water, a phenomenon often referred to as the 'salting out' effect.

Conclusion

Since all four listed factors—solubility, partial pressure, temperature, and salt levels—influence the amount of a gas dissolved in water, the correct answer includes all of them.

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Important Questions from Chemical Equilibrium

  1. The vapour pressures of water, acetone and ethanol at 293 K are 2.34 kPa, 12.36 kPa and 5.85 kPa respectively. Which of the following has the lowest boiling point?

  2. Consider the gas phase reaction 2A(g) + 3B(g) ⇌ 2C(g) at a given temperature. When 2.0 moles of A(g) are reacted with 2.0 moles of B(g), 0.8 moles of C(g) are formed at equilibrium at a total pressure of 2.0 bar. The value of the equilibrium constant, KP of this reaction at the given temperature is closest to

  3. The equilibrium dissociation energy of a diatomic molecule is 4.75 eV and its stretching frequency corresponds to 0.5 eV. The minimum energy required to dissociate the molecule in eV is

  4. For the reaction N2(g) + 3H2(g) → 2NH3(g), the thermodynamic quantity which depends upon the pressure at which equilibrium is arrived at is (superscript 'o'represents standard state)

  5. The equilibrium constant for the formation of the complex \(\rm Zn (NH_3)_4^{2+}\) at 25°C is close to:

    [Given: \(\rm E^0_{Zn^{+2}/Zn}=-0.763V\) and \(\rm E^0_{Zn(NH_3)^{+2}_4/Zn,NH_3}=-1.03V\)]

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