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Question

The depletion in atmospheric ozone layer in last century was due to :

The correct answer is
chlorofluorocarbon

Ozone Layer Depletion Cause Identified

The significant depletion observed in the atmospheric ozone layer during the last century is primarily attributed to specific human-made chemicals. Identifying the exact cause is crucial for understanding environmental impacts.

Chlorofluorocarbons Role in Ozone Depletion

Chlorofluorocarbons (CFCs) are identified as the main culprits responsible for the thinning of the ozone layer. These synthetic compounds were widely used in refrigerants, aerosols, and solvents.

Mechanism of Ozone Destruction

Once released into the atmosphere, CFCs rise to the stratosphere. Here, ultraviolet (UV) radiation from the sun breaks them down, releasing chlorine atoms.

  • A single chlorine atom can destroy many ozone ($O_3$) molecules.
  • The chemical reactions are cyclical, meaning the chlorine atom is regenerated and continues the destructive process.
  • Key reaction steps involve:
    • $Cl + O_3 \rightarrow ClO + O_2$
    • $ClO + O \rightarrow Cl + O_2$
    These reactions ultimately convert ozone ($O_3$) into ordinary oxygen ($O_2$).

The accumulation of these chlorine byproducts significantly damaged the ozone layer, particularly over the polar regions, leading to the formation of the "ozone hole".

Comparison with Other Options

While other substances listed can affect the atmosphere, they are not the primary cause of stratospheric ozone layer depletion:

  • Carbon monoxide ($CO$): Primarily an air pollutant and greenhouse gas, not directly linked to stratospheric ozone destruction.
  • Methane ($CH_4$): A potent greenhouse gas that can indirectly influence ozone levels, but CFCs have a more direct and severe impact.
  • Pesticides: Chemicals used in agriculture, posing environmental risks but not a significant factor in ozone layer depletion.

Therefore, chlorofluorocarbons are the established cause of the ozone depletion observed last century.

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Important Questions from Ozone Layer Depletion

  1. Which of the following is a catalytically inactive (or reservoir) molecule containing chlorine in stratosphere?
  2. Choose the correct statement(s)

    A. O$_3$ in stratosphere is not completely effective in shielding us from UV-B
    B. UV-A is biologically least harmful.
    C. Chapman mechanism deals with only O$_3$ formation in stratosphere.
    D. Sunscreen lotions either reflect or absorb or scatter UV-B and UV-A
    E. UV-B helps in dissociation of O$_3$ molecule in stratosphere.

    Choose the correct answer from the options given below.
  3. Ozone layer depletion is a major phenomenon in :

  4. With regard to ozone depletion over Antarctica, select the false statement :
  5. Atmospheric life times of CFCs is typically in the range :
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