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Question

With regard to ozone depletion over Antarctica, select the false statement :

The correct answer is
The heterogenous reaction CIONO$_2$(s)+ HCl(g) $\rightarrow$ Cl$_2$(g)+HNO$_3$(s) takes over PSCs

Ozone Depletion Statements Analysis

This question asks to identify the false statement related to ozone depletion over Antarctica. Analyzing the given options:

Key Factors in Antarctic Ozone Depletion

  • Option 1: Circumpolar vortex acts as a reaction chamber. This statement is true. The vortex isolates polar air, allowing chemical reactions necessary for ozone depletion to occur efficiently.
  • Option 2: Polar Stratospheric Clouds (PSCs) are formed within the vortex. This statement is true. The formation of PSCs requires the extremely low temperatures found inside the isolated polar vortex.
  • Option 3: There is very low temperature inside the vortex. This statement is true. Such low temperatures (below -78°C) are essential for PSC formation.

Heterogeneous Reaction Assessment

Option 4: The heterogeneous reaction CIONO$_2$(s)+ HCl(g) $\rightarrow$ Cl$_2$(g)+HNO$_3$(s) takes over PSCs

This statement is identified as the false statement. While heterogeneous chemical reactions occurring on the surfaces of PSCs are critical drivers of ozone depletion, this specific statement is considered incorrect.

The chemical equation represents a known reaction pathway:

$ CIONO_2(s) + HCl(g) \rightarrow Cl_2(g) + HNO_3(s) $

This reaction facilitates the release of ozone-destroying chlorine compounds. However, based on the provided answer key, this statement is designated as false.

Summary

Statements 1, 2, and 3 correctly describe conditions and processes related to Antarctic ozone depletion. Statement 4 is the false statement as indicated.

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Important Questions from Ozone Layer Depletion

  1. Which of the following is a catalytically inactive (or reservoir) molecule containing chlorine in stratosphere?
  2. Choose the correct statement(s)

    A. O$_3$ in stratosphere is not completely effective in shielding us from UV-B
    B. UV-A is biologically least harmful.
    C. Chapman mechanism deals with only O$_3$ formation in stratosphere.
    D. Sunscreen lotions either reflect or absorb or scatter UV-B and UV-A
    E. UV-B helps in dissociation of O$_3$ molecule in stratosphere.

    Choose the correct answer from the options given below.
  3. Ozone layer depletion is a major phenomenon in :

  4. Atmospheric life times of CFCs is typically in the range :
  5. The Wavelengths that are most important in the context of stratospheric ozone depletion are :
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