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Question

The compound(s) which show(s) the perovskite structure in solid state is (are)

Understanding Perovskite Structure Compounds

The perovskite structure refers to a specific crystal structure type with the general chemical formula $ABX_3$. Compounds exhibiting this structure are crucial in various fields, including materials science and chemistry.

Analyzing Potential Perovskite Compounds

We need to identify which of the given compounds fit the $ABX_3$ general formula and are known to possess the perovskite structure in the solid state.

  • Option 1: $CaTiO_3$ (Calcium Titanate)

    This compound has the formula $ABX_3$, where A = Ca, B = Ti, and X = O. Calcium titanate is a well-known example exhibiting the perovskite crystal structure.

  • Option 2: $NiFe_2O_4$ (Nickel Ferrite)

    This compound follows the $AB_2O_4$ formula, characteristic of the spinel structure, not the perovskite structure.

  • Option 3: $Fe_3O_4$ (Magnetite)

    Magnetite can be represented as $Fe^{2+}Fe_2^{3+}O_4$, which also fits the $AB_2O_4$ spinel structure, not the perovskite ($ABX_3$) structure.

  • Option 4: $CsPbI_3$ (Cesium Lead Iodide)

    This compound fits the $ABX_3$ formula, where A = Cs, B = Pb, and X = I. Halide compounds like $CsPbI_3$ are known to adopt the perovskite structure.

Identifying Correct Perovskite Structures

Based on the analysis, compounds fitting the $ABX_3$ formula and known to possess the perovskite structure are:

  • $CaTiO_3$
  • $CsPbI_3$

Therefore, the compounds exhibiting the perovskite structure are $CaTiO_3$ and $CsPbI_3$.

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Important Questions from Solid State

  1. The correct statement(s) about the structure of metal oxides is(are)
  2. The Miller indices of the crystal plane which cut through the crystal axes at (2a, -3b, -3c) is :
  3. For an inverse spinel, $AB_2O_4$, the A and B, respectively, can be
  4. When crystals of sodium chloride are heated in the presence of sodium vapor, they turn yellow. This is due to the formation of
  5. The band structure given below represents a 

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