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Question

Solid polymeric particles of diameter 20 micrometers ($\mu$m) are suspended in water such that the concentration of polymeric particles in the solution is 1% weight/volume (w/v). If the mass density of the polymeric particle is 1 g/cm$^3$, the number of polymeric particles present in 1 mL of this solution is ______ $\times 10^6$.
(Round off to one decimal place)

To determine the number of polymeric particles in 1 mL of the solution, we need to calculate the volume and mass of a single particle, then use the concentration to find the total mass of particles in 1 mL, and finally divide by the mass of a single particle.

Calculate Particle Volume

The diameter of the particles is given as $20 \, \mu\text{m}$. The radius ($r$) is half the diameter:

$r = \frac{20 \, \mu\text{m}}{2} = 10 \, \mu\text{m}$

Convert the radius to centimeters (cm), knowing that $1 \, \mu\text{m} = 10^{-4} \, \text{cm}$:

$r = 10 \times 10^{-4} \, \text{cm} = 10^{-3} \, \text{cm}$

The volume of a single spherical particle ($V_p$) is calculated using the formula $V = \frac{4}{3} \pi r^3$:

$V_p = \frac{4}{3} \pi (10^{-3} \, \text{cm})^3 = \frac{4}{3} \pi \times 10^{-9} \, \text{cm}^3$

Calculate Particle Mass

The mass density of the polymeric particle ($\rho_p$) is given as $1 \, \text{g/cm}^3$. The mass of a single particle ($m_p$) is:

$m_p = \rho_p \times V_p = (1 \, \text{g/cm}^3) \times (\frac{4}{3} \pi \times 10^{-9} \, \text{cm}^3) = \frac{4}{3} \pi \times 10^{-9} \, \text{g}$

Determine Total Particle Mass in Solution

The concentration is 1% weight/volume (w/v). This means there is 1 gram of solute (polymeric particles) for every 100 mL of solution.

For 1 mL of solution, the total mass of polymeric particles ($m_{total}$) is:

$m_{total} = \frac{1 \, \text{g}}{100 \, \text{mL}} \times 1 \, \text{mL} = 0.01 \, \text{g} = 10^{-2} \, \text{g}

Calculate Number of Particles

The number of particles ($N$) is the total mass of particles divided by the mass of a single particle:

$N = \frac{m_{total}}{m_p} = \frac{10^{-2} \, \text{g}}{\frac{4}{3} \pi \times 10^{-9} \, \text{g}}

Simplify the expression:

$N = \frac{3 \times 10^{-2}}{4 \pi \times 10^{-9}} = \frac{3}{4 \pi} \times 10^7

Now, calculate the numerical value:

$N \approx \frac{3}{4 \times 3.14159} \times 10^7 \approx \frac{3}{12.56636} \times 10^7 \approx 0.2387 \times 10^7

Express the result in the required format ($ \text{______} \times 10^6$):

$N \approx 2.387 \times 10^6

Rounding to one decimal place, the number of particles is $2.4 \times 10^6$.

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