When capacitors are connected in a series combination across a battery, the fundamental principle governing the charge distribution is that the charge stored on each capacitor is identical. This holds true regardless of the individual capacitance values of the capacitors in the series.
Let's consider two capacitors, $C_1$ and $C_2$, connected in series with a battery providing a voltage $V$.
Therefore, the magnitude of the charge $Q$ stored on each capacitor ($Q_1$ for $C_1$ and $Q_2$ for $C_2$) is the same: $Q_1 = Q_2 = Q$
The relationship between charge ($Q$), capacitance ($C$), and voltage ($V$) across a capacitor is given by the formula: $Q = C \times V$
For capacitors in series ($C_1$, $C_2$, etc.), the total voltage $V$ across the combination is the sum of the voltages across each capacitor ($V_1$, $V_2$, etc.): $V = V_1 + V_2 + ...$
Using the charge-capacitance-voltage relationship, we can write the voltage across each capacitor as $V_1 = \frac{Q_1}{C_1}$, $V_2 = \frac{Q_2}{C_2}$, and so on. Since $Q_1 = Q_2 = Q$ for a series connection, we have:
$V_1 = \frac{Q}{C_1}$ and $V_2 = \frac{Q}{C_2}$
Substituting these into the total voltage equation:
$V = \frac{Q}{C_1} + \frac{Q}{C_2} + ...$
Factoring out the common charge $Q$:
$V = Q \left( \frac{1}{C_1} + \frac{1}{C_2} + ... \right)$
The term in the parenthesis represents the reciprocal of the equivalent capacitance ($C_{eq}$) for capacitors in series:
$\frac{1}{C_{eq}} = \frac{1}{C_1} + \frac{1}{C_2} + ...$
So, the total charge supplied by the battery is $Q = C_{eq} \times V$. This confirms that the charge $Q$ is indeed the same for all capacitors in the series arrangement, irrespective of their individual capacitance values ($C_1, C_2, ...$).
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