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Question

If $ \vec{L}$ is the orbital angular momentum and $ \vec{S}$ is the spin angular momentum, then $ \vec{L} \cdot \vec{S}$ does NOT commute with

The correct answer is
$S_z$

The problem asks to identify which operator does NOT commute with the dot product of orbital angular momentum ($ \vec{L}$) and spin angular momentum ($ \vec{S}$). Two operators commute if their commutator is zero. The commutator is defined as $ [A, B] = AB - BA $. We are interested in the operator $ \vec{L} \cdot \vec{S} = L_x S_x + L_y S_y + L_z S_z $.

Commutation Analysis

We need to check the commutation relation $ [\vec{L} \cdot \vec{S}, O] $ for each option $ O $. We use the standard commutation relations for angular momentum: $ [L_i, L_j] = i \hbar \epsilon_{ijk} L_k $, $ [S_i, S_j] = i \hbar \epsilon_{ijk} S_k $, and $ [L_i, S_j] = 0 $.

Option 1: $ S_z $

Let's calculate $ [\vec{L} \cdot \vec{S}, S_z] $:

$ [\vec{L} \cdot \vec{S}, S_z] = [L_x S_x + L_y S_y + L_z S_z, S_z] $

Using linearity and the properties of commutators:

$ = [L_x S_x, S_z] + [L_y S_y, S_z] + [L_z S_z, S_z] $

We know $ [L_z S_z, S_z] = 0 $ because $ [S_z, S_z] = 0 $.

For the other terms:

$ [L_x S_x, S_z] = L_x [S_x, S_z] + [L_x, S_z] S_x $

Since $ [L_x, S_z] = 0 $ and $ [S_x, S_z] = -i \hbar S_y $:

$ = L_x (-i \hbar S_y) + (0) S_x = -i \hbar L_x S_y $

Similarly:

$ [L_y S_y, S_z] = L_y [S_y, S_z] + [L_y, S_z] S_y $

Since $ [L_y, S_z] = 0 $ and $ [S_y, S_z] = i \hbar S_x $:

$ = L_y (i \hbar S_x) + (0) S_y = i \hbar L_y S_x $

Summing the terms:

$ [\vec{L} \cdot \vec{S}, S_z] = -i \hbar L_x S_y + i \hbar L_y S_x = i \hbar (L_y S_x - L_x S_y) $

Since this result is non-zero, $ \vec{L} \cdot \vec{S} $ does NOT commute with $ S_z $.

Options 2, 3, and 4: $ L^2 $, $ S^2 $, and $ (\vec{L} + \vec{S})^2 $

Commutation with $ L^2 $: $ [\vec{L} \cdot \vec{S}, L^2] = [\sum_i L_i S_i, \sum_j L_j^2] $. Each term $ [L_i S_i, L_j^2] $ is zero because $ L_i $ commutes with $ L^2 $, and $ S_i $ acts on a different space and commutes with $ L^2 $. Thus, $ [\vec{L} \cdot \vec{S}, L^2] = 0 $.

Commutation with $ S^2 $: By symmetry, $ [\vec{L} \cdot \vec{S}, S^2] = 0 $. $ S_i $ commutes with $ S^2 $, and $ L_i $ commutes with $ S^2 $.

Commutation with $ (\vec{L} + \vec{S})^2 $: $ (\vec{L} + \vec{S})^2 = L^2 + S^2 + 2 \vec{L} \cdot \vec{S} $. The commutator is $ [\vec{L} \cdot \vec{S}, L^2 + S^2 + 2 \vec{L} \cdot \vec{S}] $. Since $ [\vec{L} \cdot \vec{S}, L^2] = 0 $, $ [\vec{L} \cdot \vec{S}, S^2] = 0 $, and $ [\vec{L} \cdot \vec{S}, 2 \vec{L} \cdot \vec{S}] = 0 $, the total commutator is $ 0 $.

Conclusion

The operator $ \vec{L} \cdot \vec{S} $ commutes with $ L^2 $, $ S^2 $, and $ (\vec{L} + \vec{S})^2 $. It does NOT commute with $ S_z $.

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Important Questions from Angular Momentum Operators Eigenvalues Clebsch Gordan

  1. An electron in the Coulomb field of a proton is in the following state of coherent superposition of orthonormal states $\psi_{nlm}$ 
    $\Psi = \frac{1}{3}\psi_{100} + \frac{1}{\sqrt{3}}\psi_{210} - \frac{\sqrt{5}}{3}\psi_{320}$ 
    Let $E_1, E_2$, and $E_3$ represent the first three energy levels of the system. A sequence of measurements is done on the same system at different times. Energy is measured first at time $t_1$ and the outcome is $E_2$. Then total angular momentum is measured at time $t_2 > t_1$ and finally energy is measured again at $t_3 > t_2$. The probability of finding the system in a state with energy $E_2$ after the final measurement is $P/9$. The value of $P$ is ______________ (in integer).

  2. $H$ is the Hamiltonian, $\vec{L}$ the orbital angular momentum and $L_z$ is the $z$-component of $\vec{L}$. The $1s$ state of the hydrogen atom in the non-relativistic formalism is an eigen function of which one of the following sets of operators?
  3. An atom with non-zero magnetic moment has an angular momentum of magnitude $\sqrt{12}\hbar$. When a beam of such atoms is passed through a Stern-Gerlach apparatus, how many beams does it split into?
  4. In the vector model of angular momentum applied to atoms, what is the minimum angle in degrees (in integer) made by the orbital angular momentum vector and the positive $z$ axis for a $2p$ electron?
  5. A particle has wavefunction 
    $\psi(x,y,z) = N ze^{-\alpha(x^2+y^2+z^2)}$, 
    where $N$ is a normalization constant and $\alpha$ is a positive constant. In this state, which one of the following options represents the eigenvalues of $L^2$ and $L_z$ respectively? 
    Some values of $Y_l^m$ are: 
    $Y_0^0 = \sqrt{\frac{1}{4\pi}}$, $Y_1^0 = \sqrt{\frac{3}{4\pi}} \cos\theta$, $Y_1^{\pm 1} = \mp \sqrt{\frac{3}{8\pi}} \sin\theta e^{\pm i\phi}$

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