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Question

Identify the statement, which best describes the second law of thermodynamics :

The correct answer is
When an isolated system undergoes a spontaneous change, the entropy of the universe increases.

Second Law of Thermodynamics Explained

The second law of thermodynamics fundamentally deals with the directionality of natural processes and the concept of entropy.

Let's analyze the options:

  • Option 1 and Option 2 describe the First Law of Thermodynamics, which states that energy is conserved and cannot be created or destroyed.
  • Option 3 describes the Third Law of Thermodynamics, which relates entropy to absolute zero temperature.
  • Option 4 states: "When an isolated system undergoes a spontaneous change, the entropy of the universe increases." This statement accurately captures a core principle of the Second Law of Thermodynamics. Spontaneous processes naturally proceed in a direction that increases the total entropy of the universe (system + surroundings). For an isolated system, the universe is just the system itself, hence its entropy increases.

Therefore, Option 4 is the best description.

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Important Questions from Thermodynamic Relations

  1. Reversible adiabatic process may be expressed as (T1/T2) equal to

  2. The relation for specific heats is given by

  3. The property relation for enthalpy change, dh is:

  4. The Joule -Thompson coefficient for an ideal gas is _______.
  5. Which of the following is correct? [h = specific enthalpy of substance, u = specific internal energy of substance, P = pressure of substance, ρ = density of substance.]

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