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Question

Which of the following statement(s) is/are true for an isothermal process ?
(a) There is no change in enthalpy
(b) There is no change in internal energy
(c) There is change in temperature
Choose the correct code :

The correct answer is
(a) and (b) only

Isothermal Process Characteristics Analysis

An isothermal process is a thermodynamic process where the temperature of the system remains constant throughout. Mathematically, this means:

$ \Delta T = 0 $

Thermodynamic Property Analysis

Let's analyze the given statements for an ideal gas undergoing an isothermal process:

  • Statement (a): There is no change in enthalpy
    Enthalpy ($H$) for an ideal gas is a function of temperature only. The change in enthalpy ($\Delta H$) can be expressed as $\Delta H = n C_p \Delta T$, where $n$ is the number of moles and $C_p$ is the molar heat capacity at constant pressure.
    Since $\Delta T = 0$ in an isothermal process, it follows that: $ \Delta H = n C_p \times 0 = 0 $ Therefore, statement (a) is true.
  • Statement (b): There is no change in internal energy
    For an ideal gas, internal energy ($U$) is also a function of temperature only. The change in internal energy ($\Delta U$) is given by $\Delta U = n C_v \Delta T$, where $C_v$ is the molar heat capacity at constant volume.
    As $\Delta T = 0$ in an isothermal process: $ \Delta U = n C_v \times 0 = 0 $ Thus, statement (b) is true.
  • Statement (c): There is change in temperature
    The definition of an isothermal process explicitly states that the temperature remains constant ($\Delta T = 0$). Therefore, there is no change in temperature.
    This statement contradicts the definition of an isothermal process and is false.

Conclusion

Based on the analysis, statements (a) and (b) are true, while statement (c) is false.

The correct code representing the true statements is (a) and (b) only.

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Important Questions from Thermodynamic Relations

  1. Reversible adiabatic process may be expressed as (T1/T2) equal to

  2. The relation for specific heats is given by

  3. The property relation for enthalpy change, dh is:

  4. The Joule -Thompson coefficient for an ideal gas is _______.
  5. Which of the following is correct? [h = specific enthalpy of substance, u = specific internal energy of substance, P = pressure of substance, ρ = density of substance.]

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