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Question

An electron with mass $m$ and charge $q$ is in the spin up state $\begin{pmatrix} 1 \\ 0 \end{pmatrix}$ at time $t = 0$. A constant magnetic field is applied along the y-axis, $\vec{B} = B_0 \hat{j}$, where $B_0$ is a constant. The Hamiltonian of the system is $H = -\hbar \omega \sigma_y$, where $\omega = \frac{q B_0}{2m} > 0$ and $\sigma_y = \begin{pmatrix} 0 & -i \\ i & 0 \end{pmatrix}$. The minimum time after which the electron will be in the spin down state along the x-axis, i.e., $\frac{1}{\sqrt{2}} \begin{pmatrix} 1 \\ -1 \end{pmatrix}$, is

The correct answer is
$\frac{\pi}{4\omega}$

Electron Spin Dynamics in a Magnetic Field

The problem asks for the minimum time required for an electron, initially in the spin up state, to transition to the spin down state along the x-axis when subjected to a magnetic field.

Initial Conditions and Hamiltonian

  • Initial state at $t=0$: $|\psi(0)\rangle = \begin{pmatrix} 1 \\ 0 \end{pmatrix}$. This represents the spin up state.
  • Hamiltonian: $H = -\hbar \omega \sigma_y$, where $\omega = \frac{q B_0}{2m} > 0$ and $\sigma_y = \begin{pmatrix} 0 & -i \\ i & 0 \end{pmatrix}$.
  • Target state: A state proportional to $\frac{1}{\sqrt{2}} \begin{pmatrix} 1 \\ -1 \end{pmatrix}$. This state corresponds to spin down along the x-axis.

Time Evolution

The time evolution of the quantum state is governed by the Schrödinger equation. The state at time $t$ is given by:

$ |\psi(t)\rangle = e^{-iHt/\hbar} |\psi(0)\rangle $

Substitute the Hamiltonian $H = -\hbar \omega \sigma_y$:

$ |\psi(t)\rangle = e^{-i(-\hbar \omega \sigma_y)t/\hbar} |\psi(0)\rangle = e^{i\omega t \sigma_y} |\psi(0)\rangle $

Calculating the Evolution Operator

The evolution operator $e^{i\omega t \sigma_y}$ can be calculated using the matrix properties. For a Pauli matrix $\sigma_k$, we have $e^{i\theta \sigma_k} = \cos(\theta) I + i \sin(\theta) \sigma_k$. Here, $k=y$ and $\theta = \omega t$. Thus:

$ e^{i\omega t \sigma_y} = \cos(\omega t) I + i \sin(\omega t) \sigma_y $ $ e^{i\omega t \sigma_y} = \cos(\omega t) \begin{pmatrix} 1 & 0 \\ 0 & 1 \end{pmatrix} + i \sin(\omega t) \begin{pmatrix} 0 & -i \\ i & 0 \end{pmatrix} $ $ e^{i\omega t \sigma_y} = \begin{pmatrix} \cos(\omega t) & 0 \\ 0 & \cos(\omega t) \end{pmatrix} + \begin{pmatrix} 0 & \sin(\omega t) \\ -\sin(\omega t) & 0 \end{pmatrix} $ $ e^{i\omega t \sigma_y} = \begin{pmatrix} \cos(\omega t) & \sin(\omega t) \\ -\sin(\omega t) & \cos(\omega t) \end{pmatrix} $

Determining the State at Time t

Now, apply the evolution operator to the initial state $|\psi(0)\rangle = \begin{pmatrix} 1 \\ 0 \end{pmatrix}$:

$ |\psi(t)\rangle = \begin{pmatrix} \cos(\omega t) & \sin(\omega t) \\ -\sin(\omega t) & \cos(\omega t) \end{pmatrix} \begin{pmatrix} 1 \\ 0 \end{pmatrix} $ $ |\psi(t)\rangle = \begin{pmatrix} \cos(\omega t) \cdot 1 + \sin(\omega t) \cdot 0 \\ -\sin(\omega t) \cdot 1 + \cos(\omega t) \cdot 0 \end{pmatrix} = \begin{pmatrix} \cos(\omega t) \\ -\sin(\omega t) \end{pmatrix} $

Finding the Transition Time

We want the electron to be in the state $\frac{1}{\sqrt{2}} \begin{pmatrix} 1 \\ -1 \end{pmatrix}$. Therefore, we need to find the smallest time $t > 0$ such that:

$ \begin{pmatrix} \cos(\omega t) \\ -\sin(\omega t) \end{pmatrix} = c \begin{pmatrix} 1 \\ -1 \end{pmatrix} $

for some proportionality constant $c$. Comparing the components:

  1. $\cos(\omega t) = c$
  2. $-\sin(\omega t) = -c \implies \sin(\omega t) = c$

From these conditions, we must have $\cos(\omega t) = \sin(\omega t)$. This implies $\tan(\omega t) = 1$. The smallest positive value for $\omega t$ that satisfies this condition is:

$ \omega t = \frac{\pi}{4} $

Solving for $t$ gives:

$ t = \frac{\pi}{4\omega} $

At this time, $c = \cos(\frac{\pi}{4}) = \frac{1}{\sqrt{2}}$, and the state is indeed $\begin{pmatrix} 1/\sqrt{2} \\ -1/\sqrt{2} \end{pmatrix} = \frac{1}{\sqrt{2}} \begin{pmatrix} 1 \\ -1 \end{pmatrix}$.

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Important Questions from Spin Electron Spin Pauli Matrices

  1. Atomic numbers of V, Cr, Fe and Zn are 23, 24, 26 and 30, respectively. Which one of the following materials does NOT show an electron spin resonance (ESR) spectra?
  2. Consider two non-identical spin $\frac{1}{2}$ particles labelled $1$ and $2$ in the spin product state $|\frac{1}{2}, \frac{1}{2}\rangle_1 |\frac{1}{2}, -\frac{1}{2}\rangle$. The Hamiltonian of the system is 
    $H = \frac{4\lambda}{\hbar^2} \vec{S}_1 \cdot \vec{S}_2$, 
    where $\vec{S}_1$ and $\vec{S}_2$ are the spin operators of particles $1$ and $2$, respectively, and $\lambda$ is a constant with appropriate dimensions. What is the expectation value of $H$ in the above state?

  3. A spin $\frac{1}{2}$ particle is in a spin up state along the $x$-axis (with unit vector $\hat{x}$) and is denoted as $|\frac{1}{2}, \frac{1}{2}\rangle_x$. What is the probability of finding the particle to be in a spin up state along the direction $\hat{x}'$, which lies in the $xy$-plane and makes an angle $\theta$ with respect to the positive $x$-axis, if such a measurement is made?
  4. Pauli spin matrices satisfy
  5. Consider a spin $S = \hbar/2$ particle in the state $| \phi \rangle = \frac{1}{3}  \begin{bmatrix}2 + i  \\2  \end{bmatrix} $. The probability that a measurement finds the state with $S_x = + \hbar/2$ is

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