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Question

An electron in the Coulomb field of a proton is in the following state of coherent superposition of orthonormal states $\psi_{nlm}$ 
$\Psi = \frac{1}{3}\psi_{100} + \frac{1}{\sqrt{3}}\psi_{210} - \frac{\sqrt{5}}{3}\psi_{320}$ 
Let $E_1, E_2$, and $E_3$ represent the first three energy levels of the system. A sequence of measurements is done on the same system at different times. Energy is measured first at time $t_1$ and the outcome is $E_2$. Then total angular momentum is measured at time $t_2 > t_1$ and finally energy is measured again at $t_3 > t_2$. The probability of finding the system in a state with energy $E_2$ after the final measurement is $P/9$. The value of $P$ is ______________ (in integer).

The initial quantum state of the electron is given by the superposition:

$ \Psi = \frac{1}{3}\psi_{100} + \frac{1}{\sqrt{3}}\psi_{210} - \frac{\sqrt{5}}{3}\psi_{320} $

Here, $E_1, E_2, E_3$ represent the energy levels corresponding to principal quantum numbers $n=1, 2, 3$. The states $\psi_{nlm}$ are orthonormal energy eigenstates.

  • $\psi_{100}$ corresponds to $n=1$ (Energy $E_1$).
  • $\psi_{210}$ corresponds to $n=2$ (Energy $E_2$).
  • $\psi_{320}$ corresponds to $n=3$ (Energy $E_3$).

Energy Measurement Outcome E2 at t1

At time $t_1$, energy is measured, yielding $E_2$. In quantum mechanics, this measurement causes the wave function to collapse into the eigenstate(s) associated with the measured eigenvalue. Here, the measured energy is $E_2$, which corresponds to the state $\psi_{210}$ ($n=2$).

After this measurement, the system's state collapses to:

$ \psi'_{1} = \psi_{210} $

Angular Momentum Measurement on Collapsed State at t2

At time $t_2 > t_1$, total angular momentum ($L^2$) is measured. The system is in the state $\psi_{210}$, which has quantum numbers $n=2, l=1, m=0$.

The operator for total angular momentum squared is $L^2$, with eigenvalues $l(l+1)\hbar^2$. For $l=1$, the eigenvalue is $1(1+1)\hbar^2 = 2\hbar^2$.

Since $\psi_{210}$ is an eigenstate of $L^2$ (with $l=1$), the measurement of $L^2$ will yield $2\hbar^2$ with certainty. This measurement does not alter the state of the system.

Therefore, the state remains:

$ \psi'_{2} = \psi_{210} $

Energy Measurement Probability at t3

At time $t_3 > t_2$, energy is measured again. The system is in state $\psi'_{2} = \psi_{210}$. This state corresponds to $n=2$, meaning its energy is precisely $E_2$.

Consequently, measuring the energy of the system in the state $\psi_{210}$ is guaranteed to yield $E_2$. The probability of finding the system with energy $E_2$ is 1.

Probability Calculation and P Value

The problem states this final probability is $P/9$. We have determined the probability to be 1.

Equating these values:

$ 1 = \frac{P}{9} $

Solving for $P$ yields:

$ P = 9 $

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Important Questions from Angular Momentum Operators Eigenvalues Clebsch Gordan

  1. $H$ is the Hamiltonian, $\vec{L}$ the orbital angular momentum and $L_z$ is the $z$-component of $\vec{L}$. The $1s$ state of the hydrogen atom in the non-relativistic formalism is an eigen function of which one of the following sets of operators?
  2. An atom with non-zero magnetic moment has an angular momentum of magnitude $\sqrt{12}\hbar$. When a beam of such atoms is passed through a Stern-Gerlach apparatus, how many beams does it split into?
  3. In the vector model of angular momentum applied to atoms, what is the minimum angle in degrees (in integer) made by the orbital angular momentum vector and the positive $z$ axis for a $2p$ electron?
  4. A particle has wavefunction 
    $\psi(x,y,z) = N ze^{-\alpha(x^2+y^2+z^2)}$, 
    where $N$ is a normalization constant and $\alpha$ is a positive constant. In this state, which one of the following options represents the eigenvalues of $L^2$ and $L_z$ respectively? 
    Some values of $Y_l^m$ are: 
    $Y_0^0 = \sqrt{\frac{1}{4\pi}}$, $Y_1^0 = \sqrt{\frac{3}{4\pi}} \cos\theta$, $Y_1^{\pm 1} = \mp \sqrt{\frac{3}{8\pi}} \sin\theta e^{\pm i\phi}$

  5. The spin $ \vec{S}$ and orbital angular momentum $ \vec{L}$ of an atom precess about $ \vec{J}$, the total angular momentum. $ \vec{J}$ precesses about an axis fixed by a magnetic field $ \vec{B}_1 = 2B_0 \hat{z}$, where $B_0$ is a constant. Now the magnetic field is changed to $ \vec{B}_2 = B_0( \hat{x} + \sqrt{2} \hat{y} + \hat{z})$. Given the orbital angular momentum quantum number $l = 2$ and spin quantum number $s = 1/2$, $ \theta$ is the angle between $ \vec{B}_1$ and $ \vec{J}$ for the largest possible values of total angular quantum number $j$ and its $z$-component $j_z$. The value of $ \theta$ (in degree, rounded off to the nearest integer) is ________
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