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Question

Which one of the following is called dry ice?

This question was previously asked in
NDA I 2018 GAT Previous Year Paper (22-Apr-2018)
The correct answer is

Solid carbon dioxide

Understanding Dry Ice: Solid Carbon Dioxide

The question asks to identify what is commonly known as dry ice among the given options. Dry ice is a widely used substance, primarily for cooling purposes.

What is Dry Ice?

Dry ice is the solid form of carbon dioxide (\( \text{CO}_2 \)). Unlike regular water ice, which melts into liquid water, dry ice undergoes a process called sublimation at standard atmospheric pressure. Sublimation means it directly changes from a solid to a gas without passing through a liquid phase. This property is why it's called "dry ice" – it doesn't leave any liquid residue as it warms up.

Analyzing the Options

Let's examine the provided options to determine which one correctly identifies dry ice:

  1. Solid carbon dioxide: This option states that dry ice is solid carbon dioxide. As discussed above, this is the correct definition of dry ice.
  2. Liquid carbon dioxide: This option describes carbon dioxide in its liquid state. Liquid carbon dioxide exists at high pressures and temperatures. It is not dry ice.
  3. Liquid nitrogen: Nitrogen is another element that can be liquefied at very low temperatures (around \(-196^\circ\text{C}\) or \(-321^\circ\text{F}\)). Liquid nitrogen is used as a cryogenic fluid for freezing and cooling, but it is not carbon dioxide and therefore not dry ice.
  4. Liquid ammonia: Ammonia (\( \text{NH}_3 \)) is a compound that can exist as a liquid. Liquid ammonia is used in refrigeration systems and for producing fertilizers, but it is not carbon dioxide and not dry ice.

Based on the scientific definition and properties, dry ice is solid carbon dioxide.

Properties and Uses of Dry Ice (Solid Carbon Dioxide)

  • Temperature: Dry ice is extremely cold, with a surface temperature of about \(-78.5^\circ\text{C}\) or \(-109.3^\circ\text{F}\).
  • Sublimation: It changes directly from solid to gas (\( \text{CO}_2 \) vapor) at standard pressure.
  • Cooling Agent: It is used for freezing items, keeping food cold during transport, and in laboratory experiments.
  • Fog Effects: When dry ice is placed in water, it creates dense fog, often used for theatrical effects.
  • Industrial Cleaning: Dry ice blasting is a method used for cleaning surfaces.

Understanding these properties reinforces why the term "dry ice" specifically refers to solid carbon dioxide.

Conclusion: Identifying Dry Ice

Comparing the definition of dry ice with the given options, it is clear that solid carbon dioxide is the correct answer. The other options represent different substances or different states of matter.

Properties of Substances Mentioned
Substance/State Description Related to Dry Ice?
Solid Carbon Dioxide Dry ice; sublimes at standard pressure. Yes, it is dry ice.
Liquid Carbon Dioxide Exists under high pressure; used in fire extinguishers, beverages. No, different state.
Liquid Nitrogen Cryogenic liquid (\(-196^\circ\text{C}\)). No, different substance.
Liquid Ammonia Used in refrigeration, fertilizers. No, different substance.

Revision Table: Key Concepts of Dry Ice

Summary of Dry Ice Facts
Concept Details
What it is Solid form of Carbon Dioxide (\( \text{CO}_2 \)).
Why it's "Dry" Sublimes (solid to gas) instead of melting.
Sublimation Point (Standard Pressure) About \(-78.5^\circ\text{C}\) or \(-109.3^\circ\text{F}\).
Common Uses Cooling, freezing, fog effects, cleaning.

Additional Information: Carbon Dioxide States

Carbon dioxide is a fascinating substance that can exist in different states under varying temperature and pressure conditions. Understanding its phase diagram helps explain why solid \( \text{CO}_2 \) (dry ice) behaves the way it does.

  • Gaseous \( \text{CO}_2 \): This is the state found in the atmosphere, exhaled by animals, and used in carbonated drinks.
  • Solid \( \text{CO}_2 \) (Dry Ice): Exists at temperatures below \(-56.6^\circ\text{C}\) (\(-69.9^\circ\text{F}\)) at pressures above 5.1 atm (the triple point). At standard atmospheric pressure (1 atm), it exists as a solid below \(-78.5^\circ\text{C}\) (\(-109.3^\circ\text{F}\)) and sublimes directly to gas above this temperature.
  • Liquid \( \text{CO}_2 \): Can only exist at pressures above the triple point (5.1 atm) and temperatures between \(-56.6^\circ\text{C}\) and \(31.1^\circ\text{C}\) (the critical point). Liquid \( \text{CO}_2 \) is often stored in pressurized cylinders.
  • Supercritical \( \text{CO}_2 \): Above the critical point (\(31.1^\circ\text{C}\) and 73 atm), \( \text{CO}_2 \) exists as a supercritical fluid, with properties between a liquid and a gas. It is used in various applications, including extraction processes.

The unique sublimation property of dry ice at standard pressure makes it distinct from regular ice and valuable for specific applications.

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