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Question

Which of the following system best represents the thermal equilibrium?

The correct answer is

Two objects of exactly the same temperature are in contact with each other -- heat can transfer freely between them, but no heat transfer is happening.

Understanding Thermal Equilibrium

Thermal equilibrium is a state where there is no net flow of heat energy between two objects or between a system and its surroundings. This occurs when the objects or the system and surroundings are at the same temperature.

Let's examine the given options to see which one best represents this state:

  1. Two objects of exactly the same temperature are in contact with each other -- heat can transfer freely between them, but no heat transfer is happening.
    • This option describes two objects at the same temperature that are in contact, allowing for potential heat transfer. However, because their temperatures are equal ($\text{T}_1 = \text{T}_2$), there is no temperature difference ($\Delta \text{T} = 0$), and therefore no net heat transfer occurs. This perfectly fits the definition of thermal equilibrium in a system where interaction is possible but no net energy flow happens.
  2. An object is heating up due to a nearby fireplace
    • If an object is heating up, its temperature is changing over time. This indicates a net flow of heat into the object from the fireplace. This is a process of reaching thermal equilibrium, not being in thermal equilibrium.
  3. A hot object and a cold object are placed next to each other.
    • When objects at different temperatures are in contact or placed near each other, heat energy will flow from the hotter object to the colder object until they reach thermal equilibrium. Since heat transfer is actively happening, the system is not yet in equilibrium.
  4. Two objects of exactly the same temperature have an impenetrable heat barrier between them.
    • This option describes objects already at the same temperature, which is a condition for thermal equilibrium. However, the "impenetrable heat barrier" means heat *cannot* transfer freely between them even if there *were* a temperature difference. While the objects *are* in thermal equilibrium individually and with respect to each other (no temperature difference), the description doesn't highlight the crucial aspect of equilibrium where contact is possible but no net flow occurs *because of* the equal temperatures. The first option better illustrates the state where the possibility of transfer exists, but is nullified by equal temperatures.

Based on the analysis, the scenario where objects at the same temperature are in contact and capable of transferring heat but aren't because of the equal temperature best represents thermal equilibrium.

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Important Questions from Thermodynamics

  1. If the work done on the system or by the system· is zero, which one of the following statements for a gas kept at a certain volume is correct?

  2. A system that does NOT allow exchange of heat with its surrounding is called

  3. A system that does NOT allow exchange of heat with its surrounding is called

  4. For a certain reaction, ΔG θ = -45 kJ/mol and ΔH θ = -90 kJ/mol at 0 °C. What is the minimum temperature at which the reaction will become spontaneous, assuming that ΔH θ  and ΔS θ  are independent of temperature?

  5. Which of the following statements correctly describes the thermodynamic classification of entropy?
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