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Question

Which of the following solutions is slightly acidic due to hydrolysis?

The correct answer is
NH$_4$Cl

Question Type: Chemical Reasoning (Hydrolysis)

Step-by-Step Solution:

Hydrolysis is the reaction of a salt with water to produce an acidic or basic solution. The acidity or basicity depends on the strength of the acid and base from which the salt is derived.

  • Option 1: NH4CH3COO: This salt is formed from a weak acid (CH3COOH) and a weak base (NH4OH). The solution will be slightly acidic or basic depending on the Ka and Kb values of the acid and base respectively. It is close to neutral.
  • Option 2: NH4Cl: This salt is formed from a weak base (NH4OH) and a strong acid (HCl). The ammonium ion (NH4+) will hydrolyze, producing H+ ions, resulting in a slightly acidic solution.
  • Option 3: Na2CO3: This salt is formed from a strong base (NaOH) and a weak acid (H2CO3). The carbonate ion (CO32-) will hydrolyze, producing OH- ions, resulting in a slightly basic solution.
  • Option 4: CH3COONa: This salt is formed from a weak acid (CH3COOH) and a strong base (NaOH). The acetate ion (CH3COO-) will hydrolyze, producing OH- ions, resulting in a slightly basic solution.

Core Logic/Pattern: The key is understanding which ions hydrolyze and whether they produce H+ or OH- ions.

Eliminating Incorrect Options: Options 1, 3, and 4 produce either neutral or basic solutions due to the hydrolysis of their constituent ions. Only NH4Cl results in a slightly acidic solution due to the hydrolysis of the ammonium ion.

Correct Answer: NH4Cl

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Important Questions from Acids, Bases & Salts

  1. When a large amount of carbon dioxide dissolves in a water body, the water becomes acidic because of the formation of which of the following acids?

  2. Which one of the following oxides is a neutral oxide?

  3. Which of the following foods would you advise to neutralise excess stomach acids?
  4. What is the primary contributor to the sour taste in foods like lemons, vinegar and yoghurt?
  5. Which of the following is a common component in toothpaste, for cleaning the teeth by neutralising the excess acid to prevent tooth decay?
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