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Question

Which of the following metals is NOT refined by electrolytic refining?

The correct answer is
sodium

Electrolytic Refining: Metals Not Processed

Electrolytic refining is a method used to purify metals. It involves using an electric current to reduce ions of the metal from an electrolyte solution onto a pure metal cathode. This process is most effective for metals that are moderately reactive.

The question asks which metal from the list is NOT refined using this technique. Let's examine the options:

  • Copper (Cu): Commonly refined electrolytically. Impure copper acts as the anode, pure copper as the cathode, and copper sulfate solution as the electrolyte.
  • Tin (Sn): Can be refined using electrolytic methods, although other methods are also used depending on purity requirements.
  • Zinc (Zn): Often refined electrolytically, especially after being obtained from smelting processes.
  • Sodium (Na): Sodium is a highly reactive alkali metal. It has a very low electrode potential. Due to its high reactivity, sodium is typically extracted by the electrolysis of its molten salts (like molten NaCl), not refined by electrolytic refining of the impure metal itself. The standard electrolytic refining setup is not suitable for such reactive metals.

Therefore, sodium is the metal that is NOT typically refined by electrolytic refining among the given choices.

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Important Questions from General Principles And Process of Isolation of Elements

  1. Froth floatation process is based on-

  2. Which of the following statements are true for the reaction of Fe2O3 with aluminium?

    1. It is known as the ‘thermite reaction’.

    2. The heat evolved is used for welding purpose.

    3. Aluminium metal acts as an oxidizing agent. 

    4. Molten Fe and Al are formed at the end of the reaction. 

    Select the correct answer using the code given below. 

  3. The metal refined by Van Arkel method is

  4. Match list I with list II

    List I

    List  II

    A.

    Siderite

    I.

    Aluminium

    B.

    Malachite

    II.

    Iron

    C.

    Calamine

    III.

    Copper

    D.

    Bauxite

    IV.

    Zinc

    Choose the correct answer from the options given below:

  5. Electrolysis as a source of extraction of metals are only successful when ________________.

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