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Question

Which of the following application of electrolysis is not covered under electro-deposition?

The correct answer is

Electro-polishing

Understanding Electro-deposition Applications

Electro-deposition is a broad term that covers various processes where a layer of material is deposited onto a substrate using electrolysis. This involves passing an electric current through an electrolyte solution containing ions of the material to be deposited. The cathode (the object receiving the deposit) attracts the positive ions, causing them to gain electrons and deposit as a solid layer.

Let's look at the options provided and see how they relate to electro-deposition:

  • Electro-polishing: This process uses electrolysis to remove a thin layer of material from the surface of a workpiece. It is essentially the reverse of electro-deposition. The workpiece acts as the anode, and material is dissolved from its surface, resulting in a smoother and brighter finish.
  • Electro-facing: This is a type of electro-deposition where a relatively thick layer of hard material, often a wear-resistant alloy like cobalt-based alloys (e.g., Stellite), is deposited onto a base metal. It is used to improve surface properties like hardness, wear resistance, and corrosion resistance.
  • Electroplating: This is the most common application of electro-deposition. A thin layer of one metal is deposited onto the surface of another material (usually metal) using an electric current. Electroplating is done for decorative purposes, corrosion protection, or to improve surface conductivity.
  • Electroforming: This is another application of electro-deposition used to create metal parts by depositing a thick layer of metal onto a mandrel or mold. Once the desired thickness is achieved, the deposited layer is separated from the mandrel to form a stand-alone object. This process allows for the creation of complex shapes and intricate details.

Identifying the Process Not Covered by Electro-deposition

Based on the descriptions above, electro-deposition involves the *deposition* of material onto a surface. Electro-facing, Electroplating, and Electroforming all fit this description, as they involve adding a layer of metal to a substrate or a mandrel.

Electro-polishing, however, is an electrolytic process that involves the *removal* of material from a surface to achieve a smooth finish. It is subtractive rather than additive.

Therefore, Electro-polishing is the application of electrolysis that is not covered under electro-deposition.

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Important Questions from Electrolysis

  1. Which of the following statements is TRUE about anodising?

  2. How much of energy is required for refining gold?

  3. The material which is to be electroplated:

  4. What is the mathematical form of Faraday’s first law of Electrolysis?

  5. In case of gold plating, the anode is of ____________.

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