The question requires identifying an ace footballer and former Indian football team captain who was selected for the Padma Shri honour in 2025.
The selected individual is IM Vijayan.
IM Vijayan is a distinguished figure in Indian football, known for his prowess as an ace footballer and his tenure as a former captain of the Indian national team. He has been selected for the prestigious Padma Shri award in the context of the year 2025, as stated in the question.