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Question

The vapour pressure over the concave surface is ______

The correct answer is
Less than the vapour pressure over the plane surface

Vapour Pressure Over Concave Surface

The relationship between vapour pressure and the curvature of a liquid surface is governed by surface tension effects.

Considerations:

  • Surface Tension: Liquid surfaces exhibit surface tension, acting like a stretched membrane. This causes a net inward pull on surface molecules.
  • Concave Surface: In a concave surface, the net effect of surface tension and molecular interactions makes it easier for molecules to escape into the vapour phase compared to a plane surface. Alternatively, the pressure difference across the interface (related to Young-Laplace equation) leads to lower vapour pressure.
  • Result: This increased tendency for evaporation leads to a lower equilibrium vapour pressure over the concave surface.

Therefore, the vapour pressure over the concave surface is less than the vapour pressure over the plane surface.

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Important Questions from Surface Tension

  1. Which of the following statements is NOT correct about surface tension?

  2. If a liquid droplet and a soap bubble are formed from the same liquid and have the same radius $R$, how does the excess pressure inside the soap bubble ($\Delta P_{bubble}$) compare to the excess pressure inside the liquid droplet ($\Delta P_{droplet}$)?

  3. Mercury does NOT wet the glass. This is due to the property of the liquid known as

  4. ________ is a surface phenomenon.

  5. A liquid drop is spherical in shape due to

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