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Question is based on the following passage:

p-block elements are placed in groups 13 to 18 of the periodic table. Group 15 is nitrogen family. Nitrogen makes various compounds like NH₃, HNO₃, N₂O, NO₂ etc. Phosphorus exists in the form of white and red phosphorus. White phosphorus glows in dark. PH₃ gas is used as smoke screen. Group 16 is called oxygen family. Dry air contains 21% O₂ gas by volume. Combined sulphur exists as sulphates such as gypsum, epsome salt, baryte etc. The allotropic forms of sulphur are Rhombic and monoclinic sulphur. S₂ is paramagnetic like O₂ and it is stable at high temperature. Group 17 is Halogen family. F₂ is highly reactive, Cl₂ is greenish yellow gas. Both SO₂ and Cl₂ are used for bleaching. Group 18 is Noble gas family but some noble gases also form compounds. Complete hydrolysis of XeF₆ gives HF and XeO₃ as main products.

The product of complete hydrolysis of XeF₆ in the following reaction is:

XeF₆ + H₂O → ? HF

The correct answer is

XeO₃F

- The complete hydrolysis of XeF₆ (Xenon hexafluoride) reacts with water to form XeO₃F, a fluorine-oxygen compound of xenon.

- This is a typical reaction for xenon fluorides where partial hydrolysis occurs, forming mixed oxides and fluorides.

- XeOF₄ and XeO₂F₂ are not the products of complete hydrolysis of XeF₆; they are formed in incomplete hydrolysis reactions.

- Therefore, the correct answer is (c) XeO₃F.

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Important Questions from Electrochemistry

  1. What is the numerical value of one Faraday in Coulombs?

  2. Which term of molar conductivity is used when the concentration of electrolyte approaches zero?

  3. Kohlrausch law is related to which of the following term?

  4. Identify transition metal complexes which are not octahedral in shape.

    (A) [Co(NH₃)₆]³⁺

    (B) [Ni(CO)₄]

    (C) [CoCl(NH₃)₅]²⁺

    (D) [CoCl₂(NH₃)₄]⁺

    (E) [PtCl₄]²⁻

    Choose the correct answer from the options given below:

  5. In a reaction A and B react to form product. The initial rate of reaction (ro) was determined using different initial concentrations of A and B as shown below:

    A/mol L-1B/mol L-1ro/mol L-1 s-1
    0.100.306.81 × 10-4
    0.100.102.27 × 10-4
    0.200.3013.62 × 10-4

    What is the initial rate of reaction (ro) when the critical concentration of A and B is 0.50 mol/L and 0.50 mol/L, respectively?

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