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Question

Question is based on the following passage:

p-block elements are placed in groups 13 to 18 of the periodic table. Group 15 is nitrogen family. Nitrogen makes various compounds like NH₃, HNO₃, N₂O, NO₂ etc. Phosphorus exists in the form of white and red phosphorus. White phosphorus glows in dark. PH₃ gas is used as smoke screen. Group 16 is called oxygen family. Dry air contains 21% O₂ gas by volume. Combined sulphur exists as sulphates such as gypsum, epsome salt, baryte etc. The allotropic forms of sulphur are Rhombic and monoclinic sulphur. S₂ is paramagnetic like O₂ and it is stable at high temperature. Group 17 is Halogen family. F₂ is highly reactive, Cl₂ is greenish yellow gas. Both SO₂ and Cl₂ are used for bleaching. Group 18 is Noble gas family but some noble gases also form compounds. Complete hydrolysis of XeF₆ gives HF and XeO₃ as main products.

The product of complete hydrolysis of XeF₆ in the following reaction is:

XeF₆ + H₂O → ? HF

The correct answer is

XeO₃F

- The complete hydrolysis of XeF₆ (Xenon hexafluoride) reacts with water to form XeO₃F, a fluorine-oxygen compound of xenon.

- This is a typical reaction for xenon fluorides where partial hydrolysis occurs, forming mixed oxides and fluorides.

- XeOF₄ and XeO₂F₂ are not the products of complete hydrolysis of XeF₆; they are formed in incomplete hydrolysis reactions.

- Therefore, the correct answer is (c) XeO₃F.

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Important Questions from Electrochemistry

  1. Identify transition metal complexes which are not octahedral in shape.

    (A) [Co(NH₃)₆]³⁺

    (B) [Ni(CO)₄]

    (C) [CoCl(NH₃)₅]²⁺

    (D) [CoCl₂(NH₃)₄]⁺

    (E) [PtCl₄]²⁻

    Choose the correct answer from the options given below:

  2. In a reaction A and B react to form product. The initial rate of reaction (ro) was determined using different initial concentrations of A and B as shown below:

    A/mol L-1B/mol L-1ro/mol L-1 s-1
    0.100.306.81 × 10-4
    0.100.102.27 × 10-4
    0.200.3013.62 × 10-4

    What is the initial rate of reaction (ro) when the critical concentration of A and B is 0.50 mol/L and 0.50 mol/L, respectively?

  3. In which of the following actinoid elements 6d subshell is vacant?

  4. Which of the following shows both, Frenkel and Schottky defect?

  5. The role of a catalyst is to change:

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