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Question

The increasing order of adsorption power of adsorbents is given by

The correct answer is

calcium carbonate < magnesia < silica gel < alumina

Understanding Adsorption Power of Common Adsorbents

Adsorption power refers to the ability of an adsorbent material to attract and hold molecules of a substance onto its surface. Different materials have different adsorption capacities based on their surface area, porosity, chemical composition, and surface polarity. Commonly used adsorbents include alumina, silica gel, magnesia, and calcium carbonate.

Comparing the Adsorption Strength

Let's look at the relative adsorption strengths of these common adsorbents:

  • Alumina (Al₂O₃): Activated alumina is a highly porous material with a large surface area. It is particularly effective at adsorbing polar molecules like water. Its adsorption power is generally high, especially for polar substances.
  • Silica Gel (SiO₂): Silica gel is another widely used adsorbent, known for its high surface area and porous structure. Like alumina, it is effective for adsorbing polar compounds. Its adsorption power is comparable to or slightly less than alumina, depending on the specific type and activation.
  • Magnesia (MgO): Magnesium oxide has a moderate surface area and can act as an adsorbent. It is sometimes used for specific applications, but its general adsorption power is typically lower than that of silica gel or alumina.
  • Calcium Carbonate (CaCO₃): Calcium carbonate is less commonly used as a general adsorbent compared to the others listed. Its surface area and porosity are generally lower, resulting in weaker adsorption power. It is often used for specific purposes, such as removing certain impurities or as a support material.

Determining the Increasing Order of Adsorption Power

Based on the typical properties and uses of these adsorbents, their increasing order of adsorption power is generally observed as:

Calcium Carbonate < Magnesia < Silica Gel < Alumina

This means that calcium carbonate has the lowest adsorption power among the four, followed by magnesia, then silica gel, and alumina typically exhibits the highest adsorption power, especially for polar substances.

Therefore, the increasing order of adsorption power of these adsorbents is calcium carbonate, followed by magnesia, then silica gel, and finally alumina.

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Important Questions from Surface Chemistry

  1. A mixture is heterogeneous and shows Tyndall effect. It stops showing Tyndall effect after it has been kept for some time. Which of the following about this mixture is correct?
  2. If a crystal of potassium permanganate is kept in a beaker containing water, the water becomes pink after some time. What characteristic of matter is inferred through this observation?

  3. The gas used in artificial ripening of green fruits is

  4. Motor vehicles equipped with catalytic converter should use unleaded petrol because lead in the petrol will cause following problem:

  5. The correct statement about chemisorption is

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