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Question

The first law of thermodynamics states about

The correct answer is
conservation of energy.

First Law of Thermodynamics Explained

The first law of thermodynamics is a core principle governing energy transfer and transformation within physical systems.

Principle of Conservation

This law fundamentally states that energy in an isolated system remains constant over time. It cannot be created or destroyed, only changed from one form to another.

  • Energy Conversion: The law highlights that energy can be converted between different forms, such as heat, work, and internal energy.
  • System Energy: For any process, the change in the internal energy of a system ($\Delta U$) is equal to the heat added to the system ($Q$) minus the work done by the system ($W$). The mathematical expression is:

    $\Delta U = Q - W$

Relation to Conservation Laws

The first law of thermodynamics is essentially an expression of the conservation of energy applied to thermodynamic processes.

Other conservation laws, like the conservation of mass or momentum, are fundamental but are described by different physical laws (e.g., Newton's laws for momentum, principles of mass continuity for mass). The increase in entropy relates to the second law of thermodynamics, not the first.

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Important Questions from Thermodynamics

  1. Second law of thermodynamics states that

    A. Energy flows from higher concentration to lower concentration.
    B. Order becomes disorder during energy transformations.
    C. The quality of energy degrades as it is transformed.
    D. Degraded energy is entropy, dessipated as waste products or heat.
    E. Enthalpy is wasted in energy transformation.

    Choose the most appropriate answer from the options given below:
  2. Choose the Incorrect Statement:
     

    1 For a system at equilibrium, chemical potential is same in all phases.
    2 Gibb's free energy change is zero at equilibrium state of a system.
    3 Gibb's free energy change is positive for reaction to occur spontaneously.
    4 $\Delta G$ will become more negative with increasing temperature.

  3. In a closed thermodynamic system, across its boundaries
  4. Melting Point of pure ice is-

  5. Which one among the following statements with reference to the properties of water is not correct?

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