The correct ascending order of the following greenhouse gases with respect to their global warming potential relative to $CO_2$ in the time horizon of 100 years is
Global Warming Potential (GWP) measures how much energy the emissions of 1 ton of a gas will trap in the atmosphere over a specific time period, relative to 1 ton of carbon dioxide ($CO_2$). A higher GWP means a gas traps more heat.
The approximate GWP values for the specified greenhouse gases over a 100-year time horizon, relative to $CO_2$ (GWP = 1), are:
Comparing these values, we can arrange the gases in ascending order of their GWP:
Therefore, the ascending order is $CH_4 < N_2O < CFCl_3 < CF_2Cl_2$.
This order corresponds to Option 1 (A).