The phenomenon described relates to the scattering of light by particles. The principle governing this is dependent on the relative size of the scattering particles compared to the wavelength of the light.
According to Rayleigh scattering, when particles are much smaller than the wavelength of light (like air molecules), they scatter shorter wavelengths more effectively than longer ones.
Very fine particles, such as the molecules in Earth's atmosphere, are significantly smaller than the wavelengths of visible light. Consequently, these particles preferentially scatter shorter wavelengths.
Reasoning: Shorter wavelengths like blue light are scattered much more strongly than longer wavelengths like red light by these tiny particles.
Therefore, very fine particles scatter mainly Blue light.
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