Steel's microstructure depends heavily on its cooling rate after heating. Quenching involves rapid cooling to transform the steel structure.
When steel is heated to its austenite phase and then rapidly cooled (quenched) in a medium like water, the cooling rate is extremely fast. This rapid cooling prevents the normal diffusion-controlled transformations that would form structures like pearlite or troostite.
The extremely rapid cooling achieved by quenching in water forces the austenite to transform into a hard, brittle, non-equilibrium phase known as Martensite. This structure is essentially a supersaturated solid solution of carbon in a body-centered tetragonal (BCT) iron lattice.
Therefore, quenching steel in water specifically results in the formation of the Martensite structure due to the drastic cooling rate.
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