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Question

Phenol is manufactured from hydrocarbon, Cumene. Cumene is chemically:

The correct answer is

Isopropyl benzene

Understanding Cumene and Phenol Manufacturing

The question asks about the chemical identity of Cumene, a hydrocarbon crucial for the manufacturing of Phenol. Phenol is an important organic chemical used in many industries. The primary industrial method for producing Phenol is the Cumene process.

What is Cumene?

Cumene is an organic compound. It's an aromatic hydrocarbon, meaning it contains a benzene ring. A key feature of Cumene is the presence of an isopropyl group attached to the benzene ring.

Let's look at the structure:

The benzene ring is represented by \(C_6H_5\). The isopropyl group is \(-CH(CH_3)_2\). So, Cumene's chemical formula is \(C_6H_5CH(CH_3)_2\).

Based on this structure, the chemical name of Cumene describes the substitution on the benzene ring. Since an isopropyl group is attached to the benzene ring, Cumene is also known by its systematic name.

Analyzing the Options

Let's examine the given options:

  1. tert. butyl benzene: A tert-butyl group has the structure \(-C(CH_3)_3\). If this group were attached to a benzene ring, it would be tert-butyl benzene. This is different from the isopropyl group in Cumene.
  2. Isopropyl benzene: An isopropyl group has the structure \(-CH(CH_3)_2\). If this group is attached to a benzene ring (\(C_6H_5\)), the compound is \(C_6H_5CH(CH_3)_2\). This structure matches that of Cumene.
  3. Acetone: Acetone is a ketone with the formula \(CH_3COCH_3\). It is used in the Cumene process as a co-product, but it is not Cumene itself.
  4. Isopropyl alcohol: Isopropyl alcohol is an alcohol with the formula \(CH_3CH(OH)CH_3\). It is related to the isopropyl group but is not an aromatic hydrocarbon like Cumene.

Conclusion: The Chemical Name of Cumene

Comparing the options with the known structure and definition of Cumene, we can see that the chemical name that correctly describes Cumene is Isopropyl benzene.

The Cumene process for manufacturing Phenol starts with Cumene (Isopropyl benzene). Cumene is oxidized to Cumene hydroperoxide, which is then cleaved (split) into Phenol and Acetone.

Key Takeaway: Cumene is Isopropyl benzene

Cumene is the common name for the compound Isopropyl benzene. This hydrocarbon is the starting material for the industrial production of Phenol via the Cumene process.

Revision Table: Key Compounds in Phenol Production

Compound Chemical Name Formula Role in Cumene Process
Cumene Isopropyl benzene \(C_9H_{12}\) (\(C_6H_5CH(CH_3)_2\)) Starting material
Phenol Hydroxybenzene \(C_6H_5OH\) Main product
Acetone Propanone \(C_3H_6O\) (\(CH_3COCH_3\)) Co-product

Additional Information about the Cumene Process and Phenol

The Cumene process is a very efficient way to produce Phenol and Acetone. It involves a few key steps:

  • Alkylation: Benzene reacts with propylene (propene) in the presence of a catalyst to form Cumene (Isopropyl benzene).
  • Oxidation: Cumene is reacted with air (oxygen) to form Cumene hydroperoxide.
  • Cleavage: Cumene hydroperoxide is treated with dilute acid to split it into Phenol and Acetone.

Phenol is an important chemical used to make plastics (like Bakelite and epoxy resins), synthetic fibers, detergents, herbicides, and pharmaceuticals.

Understanding the chemical structure and common names like Cumene (Isopropyl benzene) is essential for studying organic chemistry and industrial processes.

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Important Questions from Organic Compounds Containing Nitrogen

  1. The correct increasing order of basic strength of amine is:

    (A) C₆H₅NH₂ < NH₃ < C₆H₅CH₂NH₂ < C₂H₅NH₂ < (C₂H₅)₂NH

    (B) NH₃ < C₆H₅NH₂ < C₆H₅CH₂NH₂ < C₂H₅NH₂ < (C₂H₅)₂NH

    (C) C₆H₅CH₂NH₂ < C₆H₅NH₂ < NH₃ < C₂H₅NH₂ < (C₂H₅)₂NH

    (D) C₂H₅NH₂ < (C₂H₅)₂NH < C₆H₅NH₂ < NH₃

    (E) NH₃ < C₂H₅NH₂ < C₆H₅CH₂NH₂ < (C₂H₅)₂NH < C₆H₅NH₂

    Choose the correct answer from the options given below:

  2. In which of the following molecules carbon atom marked with asterisk (*) is a stereocentre or chiral centre?

  3. Match List-I with List-II:

    List-IList-II
    (A) Urease(I) Maltose
    (B) Maltase(II) Glucose and fructose
    (C) Invertase(III) NH₃ and CO₂
    (D) Diastase(IV) Glucose

    Choose the correct answer from the options given below:

  4. t99.9% with respect to t90% for a first-order reaction is:

  5. Predict the major product in the following reaction:

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