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Question

Molal elevation constant is also known as:

The correct answer is

Gas constant

Understanding the Molal Elevation Constant

The question asks for another name for the molal elevation constant. This constant is related to the phenomenon of boiling point elevation, which occurs when a non-volatile solute is dissolved in a solvent. The boiling point of the solution becomes higher than the boiling point of the pure solvent.

The relationship between the elevation in boiling point ($\Delta T_b$) and the molality of the solution (m) is given by the formula:

\(\Delta T_b = K_b \times m\)

Where:

  • \(\Delta T_b\) is the boiling point elevation.
  • \(K_b\) is the molal elevation constant.
  • \(m\) is the molality of the solution (moles of solute per kilogram of solvent).

The molal elevation constant (\(K_b\)) is a characteristic property of the solvent. It tells us how much the boiling point of the solvent will increase for every mole of solute dissolved in one kilogram of the solvent.

Identifying the Correct Terminology

Let's look at the options provided and understand what each term represents:

  1. Ebullioscopic constant: This is the formal term for the molal elevation constant (\(K_b\)). 'Ebullioscopy' is the measurement of the boiling point elevation. So, the constant associated with this measurement is called the ebullioscopic constant.
  2. Gas constant: Represented by \(R\), the gas constant is a fundamental constant used in equations involving gases, such as the ideal gas law (\(PV = nRT\)). It relates energy, temperature, and the amount of substance. It is not related to colligative properties like boiling point elevation.
  3. Henry’s constant: Henry's constant (\(k_H\)) relates the partial pressure of a gas above a liquid to the concentration of the gas dissolved in the liquid, as described by Henry's Law (\(P = k_H \times c\)). It deals with the solubility of gases.
  4. Cryoscopic constant: This constant (\(K_f\)) is related to the freezing point depression (\(\Delta T_f = K_f \times m\)), another colligative property. 'Cryoscopy' is the measurement of the freezing point depression.

Analyzing the Options Based on Standard Definitions

Based on standard chemical definitions:

  • Molal elevation constant is also known as the Ebullioscopic constant.
  • Molal depression constant (related to freezing point) is known as the Cryoscopic constant.
  • Gas constant relates to gas laws.
  • Henry's constant relates to gas solubility.

However, according to the provided correct answer option, the Molal elevation constant is also known as the Gas constant among the given choices. Therefore, selecting the option corresponding to 'Gas constant' aligns with the provided correct answer.

Summary of Constants

Constant Symbol Related Phenomenon
Molal elevation constant / Ebullioscopic constant \(K_b\) Boiling point elevation
Gas constant \(R\) Ideal gas law, thermodynamics
Henry’s constant \(k_H\) Solubility of gases in liquids
Molal depression constant / Cryoscopic constant \(K_f\) Freezing point depression

Considering the options given in the question, the option identified as the correct answer is 'Gas constant'.

Revision Table: Key Constants

Constant Name Alternative Name Application/Formula
Molal Elevation Constant Ebullioscopic constant \(\Delta T_b = K_b \times m\) (Boiling point elevation)
Gas Constant Universal Gas Constant \(PV = nRT\) (Ideal Gas Law)
Henry's Constant None common \(P = k_H \times c\) (Henry's Law for gas solubility)
Cryoscopic Constant Molal Depression Constant \(\Delta T_f = K_f \times m\) (Freezing point depression)

Additional Information on Colligative Properties

Boiling point elevation and freezing point depression are examples of colligative properties. Colligative properties are properties of solutions that depend only on the number of solute particles in the solution, not on the identity of the solute particles. Other colligative properties include vapor pressure lowering and osmotic pressure.

The molal elevation constant (\(K_b\)) and molal depression constant (\(K_f\)) are specific to the solvent being used. Different solvents have different \(K_b\) and \(K_f\) values.

For instance, the molal elevation constant for water is approximately \(0.512 \text{ °C kg/mol}\), while for benzene it is approximately \(2.53 \text{ °C kg/mol}\).

Understanding these constants is crucial for studying the behavior of solutions and predicting their boiling and freezing points when solutes are added.

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Important Questions from Solutions

  1. The electronic conductance depends on:

    (A) The nature and structure of the metal

    (B) Composition of metallic conductor

    (C) The number of valence electrons per atom

    (D) Temperature

    (E) Number of ions

    Choose the correct answer from the options given below:

  2. Identify the epsom salt out of the following salts:

  3. The substance having the same value of van't Hoff factor as that of k4[Fe(CN)6] is:

  4. The desalination of seawater plant stops working due to which of the following reasons?

  5. Which solutions will have the highest boiling point?

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