Melting Point of pure ice is-
The melting point is a specific temperature at which a substance changes its state from solid to liquid. For pure substances, this temperature is constant under standard pressure. Understanding the melting point of pure ice is a fundamental concept in chemistry and physics.
The melting point of pure ice is universally known to be 0 degrees Celsius (\(^{\circ}\text{C}\)). This is the temperature at which ice begins to turn into liquid water at standard atmospheric pressure.
The Kelvin scale is an absolute temperature scale, meaning that 0 K represents absolute zero, the lowest possible temperature. To convert temperatures from Celsius to Kelvin, we use a straightforward formula:
$$\text{Temperature in Kelvin (K) = Temperature in Celsius } (^{\circ}\text{C}) + 273.15$$
However, for general purposes and multiple-choice questions, the value is often approximated to 273.
Let's examine the given options based on our understanding of the melting point of pure ice:
| Option | Value | Analysis |
|---|---|---|
| 1 | 273 K | This matches the calculated melting point of pure ice when converted from \(0^{\circ}\text{C}\) to Kelvin. This is the correct melting point. |
| 2 | 0 K | 0 K represents absolute zero, the theoretical lowest possible temperature, where all molecular motion ceases. Ice melts at a much higher temperature than 0 K. |
| 3 | -273 K | Temperature cannot be negative on the Kelvin scale as 0 K is the absolute minimum. This value is incorrect. |
| 4 | 300 K | 300 K is approximately \(27^{\circ}\text{C}\) (\(300 - 273 = 27\)), which is room temperature, not the melting point of ice. |
Therefore, based on the conversion from Celsius to Kelvin, the melting point of pure ice is 273 K.
Choose the Incorrect Statement:
1 For a system at equilibrium, chemical potential is same in all phases.
2 Gibb's free energy change is zero at equilibrium state of a system.
3 Gibb's free energy change is positive for reaction to occur spontaneously.
4 $\Delta G$ will become more negative with increasing temperature.
Which one among the following statements with reference to the properties of water is not correct?
For a certain reaction, ΔG θ = -45 kJ/mol and ΔH θ = -90 kJ/mol at 0 °C. What is the minimum temperature at which the reaction will become spontaneous, assuming that ΔH θ and ΔS θ are independent of temperature?