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Question

If a particle's state function is an eigenfunction of the operator $\hat{L}^2$ with eigenvalue $30\hbar^2$, then the possible eigenvalue(s) of the operator $\hat{L}_z^2$ for the same state function is/are

Quantum Mechanics: Angular Momentum Eigenvalues

Problem Setup

We are given that a particle's state function is an eigenfunction of the angular momentum squared operator, $\\hat{L}^2$, with a specific eigenvalue. We need to find the possible eigenvalues of the angular momentum z-component squared operator, $\\hat{L}_z^2$, for this same state.

The given eigenvalue for $\\hat{L}^2$ is $30\hbar^2$.

Solution Steps

  1. Relate the given $\\hat{L}^2$ eigenvalue to the quantum number $l$. The eigenvalue of $\\hat{L}^2$ is given by the formula $l(l+1)\hbar^2$, where $l$ is the angular momentum quantum number ($l \ge 0$).

    Set the given eigenvalue equal to the formula:

    $ l(l+1)\hbar^2 = 30\hbar^2 $

    Solve for $l$:

    $ l(l+1) = 30 $

    By inspection or solving the quadratic equation $l^2 + l - 30 = 0$, we find the positive integer solution $l=5$. ($ (l+6)(l-5) = 0 \implies l=5 $ since $l \ge 0$).

  2. Determine the possible values of the magnetic quantum number, $m$. For a given $l$, the possible values of $m$ (the magnetic quantum number) range from $-l$ to $+l$ in integer steps.

    Since $l=5$, the possible values for $m$ are:

    $ m = -5, -4, -3, -2, -1, 0, 1, 2, 3, 4, 5 $

  3. Find the eigenvalues of $\\hat{L}_z^2$. The eigenvalue of $\\hat{L}_z$ is $m\hbar$. Therefore, the eigenvalue of $\\hat{L}_z^2$ is $(m\hbar)^2 = m^2\hbar^2$.

    Calculate $m^2\hbar^2$ for each possible value of $m$:

    • For $m=0$, eigenvalue $= 0^2\hbar^2 = 0$.
    • For $m=\pm 1$, eigenvalue $= (\pm 1)^2\hbar^2 = 1\hbar^2$.
    • For $m=\pm 2$, eigenvalue $= (\pm 2)^2\hbar^2 = 4\hbar^2$.
    • For $m=\pm 3$, eigenvalue $= (\pm 3)^2\hbar^2 = 9\hbar^2$.
    • For $m=\pm 4$, eigenvalue $= (\pm 4)^2\hbar^2 = 16\hbar^2$.
    • For $m=\pm 5$, eigenvalue $= (\pm 5)^2\hbar^2 = 25\hbar^2$.
  4. Identify the possible eigenvalues from the given options. The possible eigenvalues for $\\hat{L}_z^2$ are $0, \hbar^2, 4\hbar^2, 9\hbar^2, 16\hbar^2, 25\hbar^2$. Comparing these with the options provided:

    • $10\hbar^2$: Not possible, as $m^2=10$ has no integer solution for $m$.
    • $16\hbar^2$: Possible (when $m=\pm 4$).
    • $25\hbar^2$: Possible (when $m=\pm 5$).
    • $0$: Possible (when $m=0$).

Therefore, the possible eigenvalues of $\\hat{L}_z^2$ are $0$, $16\hbar^2$, and $25\hbar^2$.

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Important Questions from Angular Momentum

  1. The orbital angular momentum (L) of an electron is $\sqrt{12}\hbar$. The minimum angle between L and its z-component (in degrees) is ______ (rounded off to one decimal place).
  2. The spherical harmonic function, $Y_{l,m}(\theta,\phi)$, with appropriate values of $l$ and $m$, is an eigen function of $\hat{L}_x^2 + \hat{L}_y^2$ operator. The corresponding eigenvalue is

  3. The angle of orientation (in degrees) of the angular momentum vector with respect to z-axis for $l = 2$ and $m_l = +2$ state of H-atom is ________ (up to two decimal places)
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