[Given: Speed of light $c = 3.000 \times 10^8 \text{ m s}^{-1}$]
This problem involves calculating the observed frequency of radiation emitted by a source approaching an observer, which is an application of the Doppler effect.
When a source of radiation moves towards an observer, the observed frequency ($f_{obs}$) is higher than the emitted frequency ($f_{source}$). For speeds significantly less than the speed of light ($v \ll c$), the non-relativistic Doppler effect formula can be used.
The formula for the observed frequency when the source approaches the observer is:
$f_{obs} = f_{source} \left(1 + \frac{v}{c}\right)$
Where:
Given values:
First, calculate the ratio $\frac{v}{c}$:
$\frac{v}{c} = \frac{5.000 \times 10^6 \text{ m s}^{-1}}{3.000 \times 10^8 \text{ m s}^{-1}} = \frac{5}{300} = \frac{1}{60}$
Now, substitute this value into the Doppler effect formula:
$f_{obs} = (3.100 \times 10^9 \text{ Hz}) \left(1 + \frac{1}{60}\right)$
$f_{obs} = (3.100 \times 10^9 \text{ Hz}) \left(\frac{60+1}{60}\right)$
$f_{obs} = (3.100 \times 10^9 \text{ Hz}) \left(\frac{61}{60}\right)$
Calculate the final observed frequency:
$f_{obs} = 3.100 \times \frac{61}{60} \times 10^9 \text{ Hz}$
$f_{obs} = \frac{189.1}{60} \times 10^9 \text{ Hz}$
$f_{obs} = 3.151666... \times 10^9 \text{ Hz}$
Rounding the coefficient to three decimal places:
$f_{obs} \approx 3.152 \times 10^9 \text{ Hz}$
The observer detects a frequency of 3.152 $\times 10^9 \text{ Hz}$.
Consider the following six vibrational modes:
symmetric stretching of $CO_2$, O-H symmetric stretching of $H_2O$, stretching of HCl, stretching of $H_2$, N-H symmetric stretching of $NH_3$, and bending of $CO_2$.
Among these modes, if k number of modes are IR active but Raman inactive, l number of modes are IR inactive but Raman active, and m number of modes are both IR and Raman active.
k, l, and m, respectively, are