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Question

If a molecule emitting a radiation of frequency $3.100 \times 10^9 \text{ Hz}$ approaches an observer with a relative speed of $5.000 \times 10^6 \text{ m s}^{-1}$, then the observer detects a frequency of ________ $\times 10^9 \text{ Hz}$. (rounded off to three decimal places)
[Given: Speed of light $c = 3.000 \times 10^8 \text{ m s}^{-1}$]

This problem involves calculating the observed frequency of radiation emitted by a source approaching an observer, which is an application of the Doppler effect.

Doppler Effect Calculation for Approaching Source

When a source of radiation moves towards an observer, the observed frequency ($f_{obs}$) is higher than the emitted frequency ($f_{source}$). For speeds significantly less than the speed of light ($v \ll c$), the non-relativistic Doppler effect formula can be used.

Applying the Doppler Effect Formula

The formula for the observed frequency when the source approaches the observer is:

$f_{obs} = f_{source} \left(1 + \frac{v}{c}\right)$

Where:

  • $f_{obs}$ is the observed frequency.
  • $f_{source}$ is the frequency emitted by the source.
  • $v$ is the relative speed between the source and the observer.
  • $c$ is the speed of light.

Step-by-Step Calculation

Given values:

  • Source frequency, $f_{source} = 3.100 \times 10^9 \text{ Hz}$
  • Relative speed, $v = 5.000 \times 10^6 \text{ m s}^{-1}$
  • Speed of light, $c = 3.000 \times 10^8 \text{ m s}^{-1}$

First, calculate the ratio $\frac{v}{c}$:

$\frac{v}{c} = \frac{5.000 \times 10^6 \text{ m s}^{-1}}{3.000 \times 10^8 \text{ m s}^{-1}} = \frac{5}{300} = \frac{1}{60}$

Now, substitute this value into the Doppler effect formula:

$f_{obs} = (3.100 \times 10^9 \text{ Hz}) \left(1 + \frac{1}{60}\right)$

$f_{obs} = (3.100 \times 10^9 \text{ Hz}) \left(\frac{60+1}{60}\right)$

$f_{obs} = (3.100 \times 10^9 \text{ Hz}) \left(\frac{61}{60}\right)$

Calculate the final observed frequency:

$f_{obs} = 3.100 \times \frac{61}{60} \times 10^9 \text{ Hz}$

$f_{obs} = \frac{189.1}{60} \times 10^9 \text{ Hz}$

$f_{obs} = 3.151666... \times 10^9 \text{ Hz}$

Rounding the coefficient to three decimal places:

$f_{obs} \approx 3.152 \times 10^9 \text{ Hz}$

The observer detects a frequency of 3.152 $\times 10^9 \text{ Hz}$.

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Important Questions from Spectroscopy

  1. Consider the following six vibrational modes: 
    symmetric stretching of $CO_2$, O-H symmetric stretching of $H_2O$, stretching of HCl, stretching of $H_2$, N-H symmetric stretching of $NH_3$, and bending of $CO_2$. 
    Among these modes, if k number of modes are IR active but Raman inactive, l number of modes are IR inactive but Raman active, and m number of modes are both IR and Raman active. 
    k, l, and m, respectively, are

  2. The frequency of radiation (in cm$^{-1}$ units) required to vibrationally excite the molecule from v = 0 to v = 1 state is
  3. The frequency of radiation (in cm$^{-1}$ units) required to rotationally excite the molecule from J = 0 to J = 1 state is
  4. The correct statement(s) about Mössbauer spectroscopy of iron compounds is(are)
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