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Question

Consider the following statements regarding hydrogen bonds :

  • I. Hydrogen bonds can only form when hydrogen is bonded to oxygen, nitrogen or fluorine.
  • II. Hydrogen bonds are intramolecular only.
  • III. The strength of a hydrogen bond decreases with a decrease in the electronegativity of the two bonded atoms.

Which of the statements given above is/are not correct?

This question was previously asked in
NDA 2 2026 GAT Question Paper (13-Sep-2026)
The correct answer is

II only

Statement I is correct: hydrogen bonding occurs when hydrogen is covalently bonded to a small, highly electronegative atom such as O, N or F. Statement II is not correct: hydrogen bonds can be intermolecular (e.g. between water molecules) as well as intramolecular (e.g. in o-nitrophenol). Statement III is correct: a greater electronegativity difference gives a stronger hydrogen bond, so bond strength decreases as electronegativity of the bonded atoms decreases. Hence only statement II is not correct.

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