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Question

Consider the following statements regarding osmotic pressure.
(A) Molar mass of a protein can be determined using osmotic pressure method.
(B) The osmotic pressure is proportional to the molarity.
(C) Reverse osmosis occurs when a pressure larger than osmotic pressure is applied to the concentrated solution side.
(D) Edema occurs due to retention of water in tissue cells as a result of osmosis.
Choose the correct statements with reference to osmotic pressure :

The correct answer is
(A), (B), (C) and (D)

Osmotic Pressure Statement Analysis

This question requires evaluating four statements about osmotic pressure and identifying the correct ones.

Statement Analysis

  • Statement (A): Correct. Osmotic pressure is a colligative property, meaning it depends on the number of solute particles. For large molecules like proteins, where determining molar mass by other methods can be challenging, osmotic pressure measurement provides a reliable way to calculate molar mass using the relation $\Pi = \frac{CRT}{M}$, where M is the molar mass.
  • Statement (B): Correct. According to the Van't Hoff equation, osmotic pressure ($\Pi$) is directly proportional to the molar concentration (molarity, M) of the solute, temperature (T), and the van't Hoff factor (i), represented as $\Pi = iMRT$. When other factors are constant, $\Pi \propto M$.
  • Statement (C): Correct. Osmosis is the net movement of solvent molecules through a selectively permeable membrane into a region of higher solute concentration. Reverse osmosis is achieved by applying an external pressure to the more concentrated solution that exceeds the osmotic pressure. This forces the solvent molecules to move from the concentrated side to the less concentrated side.
  • Statement (D): Correct. Edema is the swelling caused by excess fluid accumulation in the body's tissues. Osmosis plays a critical role in regulating fluid balance. When the osmotic pressure within tissue cells or interstitial spaces increases (e.g., due to high solute concentration or low plasma protein levels), water moves into these areas via osmosis, leading to retention of water and swelling.

Conclusion

All four statements (A), (B), (C), and (D) are accurate descriptions related to osmotic pressure and its applications or consequences.

Therefore, the correct option includes all statements.

Correct Statements: (A), (B), (C), and (D)

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Important Questions from Solutions

  1. ______ forces water through a semipermeable membrane and removes contaminants

  2. Which one of the following is not a colligative property?

  3. The nature of intermolecular forces among Benzene molecule is

  4. Which of the following products are obtained when Na2CO3 is added to a solution of copper sulphate? 

  5. To prepare 1L of 5N solution of conc. HCl from 37% HCl one would need how much of HCl?

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