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Question

Consider the following nuclear electric quadrupole moments (Q) of the nuclei :

NuclideQ (in barn)
$^{133}$Cs-0.003
$^{161}$Dy+2.401
$^{63}$Cu-0.209


 

 

 

 

Which one of the following statements regarding the shape of these nuclei is correct?

The correct answer is
$^{63}$Cu is oblate, $^{133}$Cs is near spherical and $^{161}$Dy is prolate.

Understanding Nuclear Shape from Electric Quadrupole Moments

The electric quadrupole moment ($Q$) of a nucleus is a measure of its deviation from spherical symmetry. It provides insight into the nucleus's shape:

  • If $Q > 0$, the nucleus is elongated along its spin axis, referred to as a prolate shape (like a rugby ball or American football).
  • If $Q < 0$, the nucleus is flattened along its spin axis, referred to as an oblate shape (like a discus or a lentil).
  • If $Q \approx 0$, the nucleus is very close to being spherical.

Analyzing Nuclear Quadrupole Moments

Let's examine the provided quadrupole moments ($Q$) for the given nuclei:

Nuclide $Q$ (in barn)
$^{133}$Cs -0.003
$^{161}$Dy +2.401
$^{63}$Cu -0.209

Determining the Shape of Each Nucleus

Using the relationship between $Q$ and nuclear shape:

  • $^{133}$Cs: The quadrupole moment is $Q = -0.003$ barn. Since this value is very close to zero, the $^{133}$Cs nucleus is considered near spherical.
  • $^{161}$Dy: The quadrupole moment is $Q = +2.401$ barn. This is a large positive value, indicating that the $^{161}$Dy nucleus has a prolate shape.
  • $^{63}$Cu: The quadrupole moment is $Q = -0.209$ barn. This negative value indicates that the $^{63}$Cu nucleus has an oblate shape.

Conclusion on Nuclear Shapes

Based on the analysis of their electric quadrupole moments:

  • $^{63}$Cu is oblate.
  • $^{133}$Cs is near spherical.
  • $^{161}$Dy is prolate.

Therefore, the correct statement is that $^{63}$Cu is oblate, $^{133}$Cs is near spherical, and $^{161}$Dy is prolate.

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Important Questions from Miscellaneous

  1. Which one of the following statements regarding hydrogen atom and other one electron species is correct?
  2. The correct order of penetrating ability of atomic orbitals is :
  3. The correct electronic configuration of Platinum is :
  4. The element with the highest enthalpy of atomization in the first transition series is :
  5. An element forms an ion in the +IV oxidation state with electronic configuration : $4d^4 \ 5d^{10}$. Which group and period of the Modern Periodic Table does the element belong to?
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