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Question

Assume that dilution factor p for an unseeded mixture of waste and water is 0.03. The DO of the mixture is initially 9.0 mg/L and after 5 days, it has dropped to 3.0 mg/L. The reaction rate constant 'K' has been found to be 0.22 / day. Five day BOD of the water will be

The correct answer is
200 mg/L

BOD Calculation Using Dilution Test Data

This solution explains how to calculate the 5-day Biochemical Oxygen Demand (BOD5) of a wastewater sample using data from a dilution test.

Identify Given Parameters

The following parameters are provided:

  • Initial Dissolved Oxygen (DO) of the mixture: $DO_0 = 9.0$ mg/L
  • DO of the mixture after 5 days: $DO_5 = 3.0$ mg/L
  • Dilution factor (volume fraction of waste in mixture): $p = 0.03$
  • Time: $t = 5$ days
  • Reaction rate constant: $K = 0.22$ /day (Note: This value is not required for calculating BOD5 from DO depletion data).

Calculate DO Depletion

The depletion in dissolved oxygen over the 5-day period indicates the amount of oxygen consumed by microorganisms in the diluted sample due to the decomposition of organic matter.

DO Depletion = Initial DO - Final DO

$ DO_{depletion} = DO_0 - DO_5 $ $ DO_{depletion} = 9.0 \text{ mg/L} - 3.0 \text{ mg/L} = 6.0 \text{ mg/L} $

Apply 5-Day BOD Formula

The 5-day BOD of the original undiluted water sample ($BOD_{5, water}$) is calculated by adjusting the DO depletion observed in the diluted mixture using the dilution factor ($p$).

The formula is:

$ BOD_{5, water} = \frac{DO_{initial\_mix} - DO_{final\_mix}}{p} $

Substituting the calculated DO depletion:

$ BOD_{5, water} = \frac{DO_{depletion}}{p} $

Compute 5-Day BOD

Now, substitute the values into the formula:

$ BOD_{5, water} = \frac{6.0 \text{ mg/L}}{0.03} $ $ BOD_{5, water} = 200 \text{ mg/L} $

Therefore, the five-day BOD of the water sample is 200 mg/L.

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