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Question

Arrange the following in increasing order of spin only magnetic movement :
A. $Co^{2+}$
B. $Ti^{3+}$
C. $Ti^{2+}$
D. $Fe^{2+}$
E. $Sc^{3+}$
Choose the correct answer from the options given below :

The correct answer is
E < B < C < A < D

The spin-only magnetic moment ($\mu_s$) is calculated using the formula:

$ \mu_s = \sqrt{n(n+2)} \, \text{Bohr magneton (BM)} $

where '$n$' is the number of unpaired electrons.

Determining Unpaired Electrons

First, find the number of unpaired electrons for each ion:

  • E. $Sc^{3+}$: Configuration is $[Ar] 3d^0$. Number of unpaired electrons, $n=0$.
  • B. $Ti^{3+}$: Configuration is $[Ar] 3d^1$. Number of unpaired electrons, $n=1$.
  • C. $Ti^{2+}$: Configuration is $[Ar] 3d^2$. Number of unpaired electrons, $n=2$.
  • A. $Co^{2+}$: Configuration is $[Ar] 3d^7$. Number of unpaired electrons, $n=3$.
  • D. $Fe^{2+}$: Configuration is $[Ar] 3d^6$. Number of unpaired electrons, $n=4$.

Calculating Magnetic Moments

Now, calculate the magnetic moment for each ion:

  • E. $Sc^{3+}$: $n=0 \implies \mu_s = \sqrt{0(0+2)} = 0 \, \text{BM}$
  • B. $Ti^{3+}$: $n=1 \implies \mu_s = \sqrt{1(1+2)} = \sqrt{3} \approx 1.73 \, \text{BM}$
  • C. $Ti^{2+}$: $n=2 \implies \mu_s = \sqrt{2(2+2)} = \sqrt{8} \approx 2.83 \, \text{BM}$
  • A. $Co^{2+}$: $n=3 \implies \mu_s = \sqrt{3(3+2)} = \sqrt{15} \approx 3.87 \, \text{BM}$
  • D. $Fe^{2+}$: $n=4 \implies \mu_s = \sqrt{4(4+2)} = \sqrt{24} \approx 4.90 \, \text{BM}$

Ordering Ions by Magnetic Moment

Arrange the ions in increasing order of their spin-only magnetic moments:

$ 0 \, \text{BM} < 1.73 \, \text{BM} < 2.83 \, \text{BM} < 3.87 \, \text{BM} < 4.90 \, \text{BM} $

This corresponds to the order:

E < B < C < A < D

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Important Questions from Mixed Topic (CUET PG)

  1. Who was the founder of Bolshevik Communist party?
  2. What is the key guide to statecraft in the realist tradition?
  3. Chronologically arrange the events in the Cold War period.
    A. Berlin Wall is constructed
    B. Communist China joins the UN
    C. Soviet invasion of Czechoslovakia
    D. Berlin Blockade
    Choose the correct answer from the options given below:
  4. Morgenthau's principles of political realism are:
    A. Politics is rooted in permanent and unchanging human nature which is basically self centred, self-regarding and self-interested
    B. Politics is an autonomous sphere of action and cannot therefore be reduced to morals
    C. International Politics is an arena of conflicting self-interests
    D. The ethics of international relations is situational ethics which is very different from private morality
    Choose the correct answer from the options given below:

  5. Who among the following political thinkers consider the anarchical self help system to be a compelling factor for States to maximise their relative power positions?

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