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Question

A mafic magma with 'Sr' concentration of 400 ppm has undergone 60% fractional crystallization. If 'Sr' is incompatible in the mineral assemblage that crystallizes from the magma with a bulk distribution coefficient of 0.2, the concentration of 'Sr' in the residual liquid is _____________ ppm (rounded off to nearest integer).

Fractional Crystallization Sr Concentration Calculation

This problem requires calculating the concentration of Strontium (Sr) in a residual magma after fractional crystallization, using the Rayleigh equation.

Given Data Identification

  • Initial Sr concentration ($C_0$): 400 ppm
  • Percentage of fractional crystallization: 60%
  • Bulk distribution coefficient ($D$): 0.2

Calculation Steps

  1. Determine the fraction of residual liquid ($F$). If 60% has crystallized, the remaining liquid fraction is:

    $ F = 1 - 0.60 = 0.40 $

  2. Apply the Rayleigh equation for fractional crystallization to find the Sr concentration in the residual liquid ($C_L$). The formula is:

    $ C_L = C_0 \times F^{(D-1)} $

  3. Substitute the known values into the equation:

    $ C_L = 400 \, \text{ppm} \times (0.40)^{(0.2 - 1)} $

    $ C_L = 400 \, \text{ppm} \times (0.40)^{-0.8} $

  4. Calculate the value:

    $ (0.40)^{-0.8} \approx 2.09034 $

    $ C_L \approx 400 \times 2.09034 \, \text{ppm} $

    $ C_L \approx 836.14 \, \text{ppm} $

  5. Round the result to the nearest integer:

    $ C_L \approx 836 \, \text{ppm} $

The calculated concentration of Sr in the residual liquid is approximately 836 ppm. This value is consistent with the provided answer range.

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